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Six-layer electrochromic devices of indium tin oxide (ITO)/NiOxHy/WO3/ZrP-electrolyte/WO3/ITO were made by reactive dc magnetron sputtering and lamination. The WO3 layer between the acidic ZrP-based electrolyte and the NiOxHy layer served as optically passive protective layer. The optical inactivity of the protective layer could be understood from arguments based on electron density of states.

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