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Saturn's moon Enceladus harbours a global water ocean , which lies under an ice crust and above a rocky core . Through warm cracks in the crust a cryo-volcanic plume ejects ice grains and vapour into space that contain materials originating from the ocean. Hydrothermal activity is suspected to occur deep inside the porous core, powered by tidal dissipation . So far, only simple organic compounds with molecular masses mostly below 50 atomic mass units have been observed in plume material. Here we report observations of emitted ice grains containing concentrated and complex macromolecular organic material with molecular masses above 200 atomic mass units. The data constrain the macromolecular structure of organics detected in the ice grains and suggest the presence of a thin organic-rich film on top of the oceanic water table, where organic nucleation cores generated by the bursting of bubbles allow the probing of Enceladus' organic inventory in enhanced concentrations.

The intense plume activity at the South Pole of Enceladus together with the recent detection of libration hints at an internal water ocean underneath the outer ice shell. However, the interpretation of gravity, shape, and libration data leads to contradicting results regarding the depth of ocean/ice interface and the total volume of the ocean. Here we develop an interior structure model consisting of a rocky core, an internal ocean, and an ice shell, which satisfies simultaneously the gravity, shape, and libration data. We show that the data can be reconciled by considering isostatic compensation including the effect of a few hundred meter thick elastic lithosphere. Our model predicts that the core radius is 180–185 km, the ocean density is at least 1030 kg/m3, and the ice shell is 18–22 km thick on average. The ice thicknesses are reduced at poles decreasing to less than 5 km in the south polar region.

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