A stable colloid of g-C3N4 nanosheets was prepared on a large scale via a H2SO4 exfoliation route. The amphoteric nature due to the simultaneous presence of carboxyl and amino groups provided a strategy to fabricate heterostructures by an electrostatic re-assembly between g-C3N4 nanosheets and various charged guests in different pH systems.
The reaction pathways to synthesize Zr 2 P 2 WO 12 (ZPW) from ZrO 2 , WO 3 , and P 2 O 5 are studied. It is found that there exist two different reaction pathways: One is direct reaction, while another is through an intermediate phase ZrP 2 O 7 . The reaction pathways are determined by drying and sintering temperatures. By controlling the reaction pathways, namely avoiding the intermediate phase, negative thermal expansion ceramic ZPW can be synthesized within several minutes. Besides, as-synthesized specimens possess much smaller and uniform grain size distribution than those synthesized by conventional methods. The investigation paves a way toward rapid and environmental friendly synthesis of ZPW and related compounds.
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