We have been investigating TiO 2 electrode which is used in marine microbial fuel cell. This study is focused on the film forming process for the electrode. We introduced screen printing and annealing for the improvement of photo-potential properties. A uniform film was formed by an introduction of screen printing. It improved the durability of electrodes and the reproducibility of photo-potential repetition. The important factor to improve photocatalytic properties is oxygen defect. Oxygen defect in TiO 2 film can be evaluated from O/Ti value. And O/Ti value of TiO 2 film can be controlled by the heat treatment temperature. There is a relationship between photo-potential and O/Ti value of TiO 2 film. Photo-potentials shifted to be active as O/Ti value decreased. As a result, photo-potential properties were also improved by introducing annealing.
It is effective to recover waste heat to reduce primary energy consumption. From this point of view, we proposed and examined a new idea of heat transportation using ammonia–water as the working fluid in the system named the Solution Transportation Absorption chiller (STA). As waste heat sources are not necessarily located close to areas of heat demand, conventionally, absorption chillers are located on heat source side and produce chilled water that is transported to heat demand side through pipelines with an insulation. In contrast, the proposed system STA divides an absorption chiller into two parts. The generator and the condenser are located on heat source side while the evaporator and the absorber are on heat demand side. Both the conventional system and STA system satisfy the same boundary condition of heat recovery and heat supply to the demand side, STA can work for transferring thermal energy as the conventional system does even though the temperature of the media is ambient without an insulation. Our previous studies of the STA were based on the experimental investigation with the STA facility where the cooling power was 90[Formula: see text]kW (25.6 refrigeration ton) at the generator temperature 120[Formula: see text]C from 0[Formula: see text]m (normal absorption chiller) to 1000[Formula: see text]m. Thus, the Coefficient of Performance (COP) of STA was found to have almost the same value of 0.65 with conventional absorption chillers without depending on the transportation distances. The objective of this study is to examine the effect of generator temperature from 100[Formula: see text]C to 120[Formula: see text]C on the performance of solution transportation of ammonia–water solution, because the generator temperature is directly linked to the waste heat temperature, so its effect needs to be investigated. The experimental facility tested the performance with 0[Formula: see text]m (normal absorption chiller), 200[Formula: see text]m and 500[Formula: see text]m distance. The results indicate that the effect of the generator temperature and solution transportation distances showed no significant on the COP.
Utilization of wasted heat instead of fuel combustion is effective to reduce primary energy consumption for mitigating global warming problem. Because wasted heat sources are not necessarily located close to areas of heat demand, one of the difficulties is that wasted heat has to be transferred from heat source side to heat demand side, which may require heat transportation over long distance. From this point we proposed and have examined new idea of heat transportation using ammonia-water as the working fluid which system is named Solution Transportation Absorption chiller, in short STA. Our previous studies of STA were mainly the experimental investigation with STA facility which cooling power was 25RT (90kW). As a result, the COP of STA was found almost same value 0.65 with the conventional absorption chiller without depending on the transportation distances. The simulation using AspenHYSYS also examined with same experimental condition. The experimental data showed good agreement with the simulation calculation. In this study, we examined the large-scale cooling power STA on simulation. The examination cooling powers were from 90 kW (25RT) to 3517 kW (1000RT). All cooling power achieved around COP 0.64 including pump power consumptions. In addition, we performed the dynamic simulation. As the results, there was no effect of pipeline size on the cooling capacities and mass flow rates. Furthermore, the stability time of the cooling capacities and mass flow rates were almost same regardless of the pipeline size and cooling capacity. In other words, STA may be achieved the same COP even though having various complex conditions compared with the conventional absorption chiller.
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