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Continuous carbon fiber reinforced polymer composite 3D printing has drawn more attention due to its ability to manufacture composite structures with complex shapes. The surface treatment of CF is necessary to improve the combination between carbon fiber (CF) and matrix. In this work, polyurethane with nano‐SiO2 (PU/SiO2) was used to size CF to enhance the compatibility of CF and nylon 6 (PA6). The chemistry and morphology of the CF were characterized by Fourier transform infrared spectroscopy (FTIR), X‐ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). The interface strength between CF and PA6 was tested by the fiber pull‐out test, and eventually obtained optimized concertation of PU/SiO2 sizing agents (with 25 wt% PU and 0.4 wt% nano‐SiO2). The results show that compared with untreated CF, the interfacial shear strength (IFSS) of CF and PA6 after sizing increased by 316.93%. In addition, several CF/PA6 composite specimens printed by a homemade composite 3D printer were used to do mechanical tests. The results show that the flexural strength increased by 33.87%, the tensile strength increased by 20.75%, and the interlaminar shear strength (ILSS) increased by 66.54%.

This study was to solve the mandrel demolding problem after curing the composite component with complex structure. In this paper, a reusable thermoplastic mandrel with heating softening characteristics was developed by resin transfer molding (RTM). The glass transition temperature (Tg), surface roughness, and reusability of the mandrel, as well as the shape, surface roughness, thickness uniformity, and internal quality of the formed structure, were tested. The result showed that the Tg of the mandrel was between 80 and 90 °C and the surface roughness was less than Ra 0.5 μm. Additionally, the mandrel can be recycled and can still maintain a good shape after 20 times of deformation. By using this method, the demolding process can be realized by heating and softening the mandrel. The profile error of the formed structure was within 0.5 mm, the surface roughness was less than Ra 0.5 μm, the thickness error was within 0.2 mm, and the average porosity of the upper and lower halves of composite parts was 0.72% and 0.61%. All those data showed that the formed part was in good shape and of good quality. The thermoplastic mandrel can solve the demolding problem of composite materials with complex shapes.

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