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A periodically driven two-state dynamics, being analysed within the Floquet formalism, exhibits localization of the amplitude dynamics in an infinite frequency range, extending from the bare tunnel splitting up to infinity. In contrast, the suppression of tunnelling in a driven symmetric double well is restricted to a limited frequency regime, extending from the bare tunnel splitting up to the first resonance frequency with higher-lying states. With the amplitude dynamics of a periodically driven two-level system not being restricted to describe coherent tunnelling transport only, the localization phenomenon within the infinite frequency range does allow for novel applications for systems in strong laser fields.

We study electron transport across a carbon molecular junction consisting of a C 60 molecule sandwiched between two semi-infinite metallic carbon nanotubes. It is shown that the Landauer conductance of this carbon hybrid system can be tuned within orders of magnitude not only by varying the tube-C 60 distance, but more importantly at fixed distances by ͑i͒ changing the orientation of the Buckminsterfullerene or ͑ii͒ rotating one of the tubes around its cylinder axis. Furthermore, it is explicitly shown that structural relaxation determines qualitatively the transmission spectrum of such devices.

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The exact stochastic decomposition of non-Markovian dissipative quantum dynamics is combined with the time-dependent semiclassical initial value formalism. It is shown that even in the challenging regime of moderate friction and low temperatures, where non-Markovian effects are substantial, this approach allows for the accurate description of dissipative dynamics in anharmonic potentials over many oscillation periods until thermalization is reached. The problem of convergence of the stochastic average at long times, which plagues full quantum mechanical implementations, is avoided through a joint sampling of the stochastic noise and the semiclassical phase-space distribution.

We analytically derive a correlated approach for a mixed semiclassical many particle dynamics, treating a fraction of the degrees of freedom by the multitrajectory semiclassical initial value method of Herman and Kluk [Chem. Phys. 91, 27 (1984)] while approximately treating the dynamics of the remaining degrees of freedom with fixed initial phase space variables, analogously to the thawed Gaussian wave packet dynamics of Heller [J. Chem. Phys. 62, 1544 (1975)]. A first application of this hybrid approach to the well studied Secrest-Johnson [J. Chem. Phys. 45, 4556 (1966)] model of atom-diatomic collisions is promising. Results close to the quantum ones for correlation functions as well as scattering probabilities could be gained with considerably reduced numerical effort as compared to the full semiclassical Herman-Kluk approach. Furthermore, the harmonic nature of the different degrees of freedom can be determined a posteriori by comparing results with and without the additional approximation.

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