Cobalt-and nickel-free cathode materials are desirable for developing low-cost sodium-ion batteries (SIBs). Compared to the single P-type and O-type structures, biphasic P/O structures become a topic of interest thanks to improved performance. However, the added complexity complicates the understanding of the storage mechanism and the phase behavior is still unclear, especially over consecutive cycling. Here, the properties of biphasic P2(34%)/O3(60%) Na 0.8 Li 0.2 Fe 0.2 Mn 0.6 O 2 and its behavior at different states of charge/discharge are reported on. The material is composed of single phase O3 and P2/O3 biphasic particles. Sodium occupies the alkali layers, whereas lithium predominantly (95%) is located in the transition metal layer. An initial reversible capacity of 174 mAh g-1 is delivered with a retention of 82% dominated by Fe 3+ /Fe 4+ along with contributions from oxygen and partial Mn 3+/4+ redox. Cycling leads to complex phase transitions and ion migration. The biphasic nature is nevertheless preserved, with lithium acting as the structure stabilizer.
The different spin configurations in the vicinity of the single-domain/vortex transition are reported in isolated magnetic nanoparticles. By combining chemical synthesis, electron holography in a dedicated transmission electron microscope and micromagnetic simulations, we establish the "magnetic configurations vs size" phase diagram of Fe single-crystalline nanocubes. Room temperature high resolution magnetic maps reveal the transition between single-domain and vortex states for Fe nanocubes from 25 to 27 nm, respectively. An intermediate spin configuration consisting of an ⟨111⟩ vortex is for the first time evidenced.
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