No abstract

Abstract. In the southwestern coastal region of Bangladesh, options for drinking water are limited by groundwater salinity. To protect and improve the drinking water supply, the large variation in groundwater salinity needs to be better understood. This study identifies the palaeo and present-day hydrological processes and their geographical or geological controls that determine variation in groundwater salinity in Upazila Assasuni in southwestern Bangladesh. Our approach involved three steps: a geological reconstruction, based on the literature; fieldwork to collect high-density hydrological and lithological data; and data processing to link the collected data to the geological reconstruction in order to infer the evolution of the groundwater salinity in the study area. Groundwater freshening and salinization patterns were deduced using PHREEQC cation exchange simulations and isotope data were used to derive relevant hydrological processes and water sources. We found that the factor steering the relative importance of palaeo and present-day hydrogeological conditions was the thickness of the Holocene surface clay layer. The groundwater in aquifers under thick surface clay layers is controlled by the palaeohydrological conditions prevailing when the aquifers were buried. The groundwater in aquifers under thin surface clay layers is affected by present-day processes, which vary depending on present-day surface elevation. Slightly higher-lying areas are recharged by rain and rainfed ponds and therefore have fresh groundwater at shallow depth. In contrast, the lower-lying areas with a thin surface clay layer have brackish–saline groundwater at shallow depth because of flooding by marine-influenced water, subsequent infiltration and salinization. Recently, aquaculture ponds in areas with a thin surface clay layer have increased the salinity in the underlying shallow aquifers. We hypothesize that to understand and predict shallow groundwater salinity variation in southwestern Bangladesh, the relative elevation and land use can be used as a first estimate in areas with a thin surface clay layer, while knowledge of palaeohydrogeological conditions is needed in areas with a thick surface clay layer.

The acceptance of newly implemented, safe drinking water options is not guaranteed. In the Khulna and Satkhira districts, Bangladesh, pond water is pathogen-contaminated, while groundwater from shallow tubewells may be arsenic-or saline-contaminated. This study aims to determine why, as well as the extent to which, people are expected to remain attached to using these unsafe water options, compared to the following four safer drinking water options: deep tubewells, pond sand filters, vendor water, and rainwater harvesting. Through 262 surveys, this study explores whether five explanatory factors (risk, attitude, norms, reliability, and habit) pose barriers to switching from unsafe to safe drinking water options or whether they could act as facilitators of such a switch. Users' attachment to using pond water is generally low (facilitators: risk and attitude. Barrier: norms). Users are more attached to shallow tubewells (no facilitators. Barriers: reliability and habit). The safe alternatives (deep tubewell, rain water harvesting, pond sand filter, and vendor water) score significantly better than pond water and are estimated to have the potential to be adopted by pond water users. Deep tubewell, rain water harvesting, and pond sand filter also score better than shallow tubewells and could also have the potential to replace them. These findings may be used to optimise implementation strategies for safer drinking water alternatives.

Riverbank filtration (RBF) systems along rivers are widely used as public water supplies. In these systems, many organic micropollutants (OMPs) are attenuated, but some compounds have shown to be rather persistent. Their fate and transport has been studied in RBF sites along lakes and small rivers, but not extensively along large and dynamic rivers. Therefore, the influence of flood events on OMP behavior in these large and dynamic RBF sites was investigated. Monthly samples were taken from surface- and groundwater up to a distance of 900 m from the riverbank of the Danube from March 2014 till May 2016. Two flood events were sampled more extensively nearby the river. Results showed that changes in flow conditions in the river not only caused changes in OMP concentrations, but also in their load. It was seen that the load of benzotriazole, carbamazepine and sulfamethoxazole in the river increased with increasing river discharges. After a relatively long, oxic groundwater passage, several OMPs were reduced. In contrast to previous work, we found that benzotriazole was almost fully removed under oxic conditions. When entering the aquifer, benzotriazole concentrations were significantly reduced and at a distance of 550 m from the river, >97% was degraded. Carbamazepine and sulfamethoxazole showed relatively persistent behavior in the aquifer. The concentrations measured during flood events were in the same range as seasonal sampling. Furthermore concentrations in the groundwater were higher during these events than in the Danube and can reach further into the aquifer. During flood events some highly degradable compounds (i.e. diclofenac) were found up to a distance of 24 m from the river. These results implied that drinking water utilities with RBF wells in oxic, alluvial aquifers located close to highly dynamic rivers need to consider a potential reduction in groundwater quality during and directly after flood events.

Abstract. In the southwestern coastal region of Bangladesh, options for drinking water are limited by groundwater salinity. To protect and improve the drinking water supply, the large variation in groundwater salinity needs to be better understood. This study identifies the palaeo and present-day hydrological processes and their geographical or geological controls that determine variation in groundwater salinity in Upazila Assasuni in southwestern Bangladesh. Our approach involved three steps: a geological reconstruction, based on the literature; fieldwork to collect high density hydrological and lithological data; and data processing to link the collected data to the geological reconstruction in order to infer the evolution of the groundwater salinity in the study area. Groundwater freshening and salinization patterns were deduced using PHREEQC cation exchange simulations and isotope data was used to derive relevant hydrological processes and water sources. We found that the factor steering the relative importance of palaeo and present-day hydrogeological conditions was the thickness of the Holocene surface clay layer. The groundwater in aquifers under thick surface clay layers is controlled by the palaeohydrological conditions prevailing when the aquifers were buried. The groundwater in aquifers under thin surface clay layers is affected by present-day processes, which vary depending on present-day surface elevation. Slightly higher-lying areas are recharged by rain and rainfed ponds and therefore have fresh groundwater at shallow depth. In contrast, the lower-lying areas with a thin surface clay layer have brackish–saline groundwater at shallow depth because of flooding by marine-influenced water, subsequent infiltration and salinization. Recently, aquaculture ponds in areas with a thin surface clay layer have increased the salinity in the underlying shallow aquifers. We hypothesize that to understand and predict shallow groundwater salinity variation in southwestern Bangladesh, the relative elevation and land use can be used as a first estimate in areas with a thin surface clay layer, while knowledge of palaeohydrogeological conditions is needed in areas with a thick surface clay layer.