We report evidence of paleo–cold seep associated activities, preserved in methane‐derived carbonates in association with chemosynthetic clams (Calyptogena sp.) from a sediment core in the Krishna‐Godavari basin, Bay of Bengal. Visual observations and calculations based on high‐resolution wet bulk density profile of a core collected on board R/V Marion Dufresne (May 2007) show zones of sharp increase in carbonate content (10–55 vol %) within 16–20 meters below seafloor (mbsf). The presence of Calyptogena clam shells, chimneys, shell breccias with high Mg calcite cement, and pyrite within this zone suggest seepage of methane and sulfide‐bearing fluid to the seafloor in the past. Highly depleted carbon isotopic values (δ13C ranges from −41 to −52‰ VPDB) from these carbonates indicate carbon derived via anaerobic oxidation of methane. Extrapolated mean calendar age (∼58.7 ka B.P.) of the clastic sediments at a depth of 16 mbsf is close to the upper limit of the U‐Th based depositional age (46.2 ± 3.7 and 53.0 ± 1.6 ka) of authigenic carbonates sampled from this level, thereby constraining the younger age limit of the carbonate deposition/methane expulsion events. The observed carbonate deposition might have resulted from the flow of methane‐enriched fluids through the fracture network formed because of shale diapirism.

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In this study, we integrate environmental magnetic, sedimentological, and geochemical records of sediment core of Hole NGHP-01-10D overlying methane hydrate deposits to decipher the controls on the evolution of fracture-filled gas-hydrate system in the Krishna-Godavari (K-G) basin. Four distinct sedimentary units have been identified, based on the sediment magnetic signatures. An anomalous zone of enhanced magnetic susceptibility (Unit III: 51.9-160.4 mbsf) coinciding with the gas hydrate bearing intervals is due to the presence of magnetite-rich detrital minerals brought-in by the river systems as a result of higher sedimentation events in K-G basin and has no influence over hydrate formation. A strong to moderate correlation between magnetite concentration and chromium reducible sulfur (CRS) content indicates significant influence of sulfidization on the magnetic record and could be further exploited as a proxy to decipher paleo-H 2 S seepage events. Analysis of high-resolution seismic, bathymetry, and subbottom profiler data reveals the existence of a regional fault system in K-G basin. The opening and closing dynamics of the faults facilitated the migration and trapping of required gas concentrations resulting in accumulation of gas hydrates at the studied site. The seismic data provides support to the rock-magnetic interpretations. The observed variations in magnetic and geochemical properties have resulted from the episodic flow of methane and sulfide-enriched fluids through the fracture-filled network formed as a result of shale-tectonism. Our study demonstrated the potential of using an enviro-magnetic approach in combination with other proxies to constrain the evolution of gas-hydrate system in marine environments. Key Points:Magnetic signatures of detrital and diagenetic processes associated with evolution of gas-hydrate system. Changes in magnetic and geochemical properties controlled by underlying gas-hydrates. Magnetic proxy to decipher paleo-H2S seepage events in marine sediments.

[1] Magnetic iron minerals are widespread and indicative sediment constituents in estuarine, coastal and shelf systems. We combine environmental magnetic, sedimentological and numerical methods to identify magnetite-enriched placer-like zones in a complex coastal system and delineate their formation mechanisms. Magnetic susceptibility and remanence measurements on 245 surficial sediment samples collected in and around Tauranga Harbour, the largest barrier-enclosed tidal estuary of New Zealand, reveal several discrete enrichment zones controlled by local hydrodynamic conditions. Active magnetite enrichment takes place in tidal channels, which feed into two coast-parallel nearshore magnetite-enriched belts centered at water depths of 6-10 m and 10-20 m. A close correlation between magnetite content and magnetic grain size was found, where higher susceptibility values are associated within coarser magnetic crystal sizes. Two key mechanisms for magnetite enrichment are identified. First, tide-induced residual currents primarily enable magnetite enrichment within the estuarine channel network. A coast-parallel, fine sand magnetite enrichment belt in water depths of less than 10 m along the barrier island has a strong decrease in magnetite ©2012. American Geophysical Union. All Rights Reserved.1 of 20 content away from the southern tidal inlet and is apparently related to active coast-parallel transport combined with mobilizing surf zone processes. A second, less pronounced, but more uniform magnetite enrichment belt at 10-20 m water depth is composed of non-mobile, medium-coarse-grained relict sands, which have been reworked during post-glacial sea level transgression. We demonstrate the potential of magnetic methods to reveal and differentiate coastal magnetite enrichment patterns and investigate their formative mechanisms.

We evaluate the environmental magnetic, geochemical, and sedimentological records from three sediment cores from potential methane-hydrate bearing sites to unravel linkages between sedimentation, shale tectonics, magnetite enrichment, diagenesis, and gas hydrate formation in the Krishna-Godavari basin. Based on downcore rock magnetic variations, four sedimentary magnetic property zones (I-IV) are demarcated. A uniform band of enhanced magnetic susceptibility (zone III) appears to reflect a period of high-sedimentation events in the Krishna-Godavari basin. Highly pressurized sedimentary strata developed as a result of increased sedimentation that triggered the development of a fault system that provided conduits for upward methane migration to enter the gas hydrate stability zone, leading to the formation of gas hydrate deposits that potentially seal the fault system. Magnetic susceptibility fluctuations and the presence of iron sulfides in a magnetically enhanced zone suggest that fault system growth facilitated episodic methane venting from deeper sources that led to multiple methane seepage events. Pyrite formation along sediment fractures resulted in diagenetic depletion of magnetic signals and potentially indicates paleo sulfate-methane transition zone positions. We demonstrate that a close correlation between magnetic susceptibility and chromium reducible sulfur concentration can be used as a proxy to constrain paleomethane seepage events. Our findings suggest that the interplay between higher sedimentation events and shale tectonism facilitated fluid/gas migration and trapping and the development of the gas hydrate system in the Krishna-Godavari basin. The proposed magnetic mineralogical approach has wider scope to constrain the understanding of gas hydrate systems in marine sediments.

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