Atmospheric carbon dioxide concentrations and climate are regulated on geological timescales by the balance between carbon input from volcanic and metamorphic outgassing and its removal by weathering feedbacks; these feedbacks involve the erosion of silicate rocks and organic-carbon-bearing rocks. The integrated effect of these processes is reflected in the calcium carbonate compensation depth, which is the oceanic depth at which calcium carbonate is dissolved. Here we present a carbonate accumulation record that covers the past 53 million years from a depth transect in the equatorial Pacific Ocean. The carbonate compensation depth tracks long-term ocean cooling, deepening from 3.0-3.5 kilometres during the early Cenozoic (approximately 55 million years ago) to 4.6 kilometres at present, consistent with an overall Cenozoic increase in weathering. We find large superimposed fluctuations in carbonate compensation depth during the middle and late Eocene. Using Earth system models, we identify changes in weathering and the mode of organic-carbon delivery as two key processes to explain these large-scale Eocene fluctuations of the carbonate compensation depth.

We report evidence of paleo–cold seep associated activities, preserved in methane‐derived carbonates in association with chemosynthetic clams (Calyptogena sp.) from a sediment core in the Krishna‐Godavari basin, Bay of Bengal. Visual observations and calculations based on high‐resolution wet bulk density profile of a core collected on board R/V Marion Dufresne (May 2007) show zones of sharp increase in carbonate content (10–55 vol %) within 16–20 meters below seafloor (mbsf). The presence of Calyptogena clam shells, chimneys, shell breccias with high Mg calcite cement, and pyrite within this zone suggest seepage of methane and sulfide‐bearing fluid to the seafloor in the past. Highly depleted carbon isotopic values (δ13C ranges from −41 to −52‰ VPDB) from these carbonates indicate carbon derived via anaerobic oxidation of methane. Extrapolated mean calendar age (∼58.7 ka B.P.) of the clastic sediments at a depth of 16 mbsf is close to the upper limit of the U‐Th based depositional age (46.2 ± 3.7 and 53.0 ± 1.6 ka) of authigenic carbonates sampled from this level, thereby constraining the younger age limit of the carbonate deposition/methane expulsion events. The observed carbonate deposition might have resulted from the flow of methane‐enriched fluids through the fracture network formed because of shale diapirism.

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Vertical seismic profiling (VSP), an established technique, can be used for estimating in‐situ anisotropy that might provide valuable information for characterization of reservoir lithology, fractures, and fluids. The P‐wave slowness components, conventionally measured in multiazimuth, walkaway VSP surveys, allow one to reconstruct some portion of the corresponding slowness surface. A major limitation of this technique is that the P‐wave slowness surface alone does not constrain a number of stiffness coefficients that may be crucial for inferring certain rock properties. Those stiffnesses can be obtained only by combining the measurements of P‐waves with those of S (or PS) modes. Here, we extend the idea of Horne and Leaney, who proved the feasibility of joint inversion of the slowness and polarization vectors of P‐ and SV‐waves for parameters of transversely isotropic media with a vertical symmetry axis (VTI symmetry). We show that there is no need to assume a priori VTI symmetry or any other specific type of anisotropy. Given a sufficient polar and azimuthal coverage of the data, the polarizations and slownesses of P and two split shear (S1 and S2) waves are sufficient for estimating all 21 elastic stiffness coefficients cij that characterize the most general triclinic anisotropy. The inverted stiffnesses themselves indicate whether or not the data can be described by a higher‐symmetry model. We discuss three different scenarios of inverting noise‐contaminated data. First, we assume that the layers are horizontal and laterally homogeneous so that the horizontal slownesses measured at the surface are preserved at the receiver locations. This leads to a linear inversion scheme for the elastic stiffness tensor c. Second, if the S‐wave horizontal slowness at the receiver location is unknown, the elastic tensor c can be estimated in a nonlinear fashion simultaneously with obtaining the horizontal slowness components of S‐waves. The third scenario includes the nonlinear inversion for c using only the vertical slowness components and the polarization vectors of P‐ and S‐waves. We find the inversion to be stable and robust for the first and second scenarios. In contrast, errors in the estimated stiffnesses increase substantially when the horizontal slowness components of both P‐ and S‐waves are unknown. We apply our methodology to a multiazimuth, multicomponent VSP data set acquired in Vacuum field, New Mexico, and show that the medium at the receiver level can be approximated by an azimuthally rotated orthorhombic model.

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Anisotropic attenuation can provide sensitive attributes for fracture detection and lithology discrimination. This paper analyzes measurements of the P-wave attenuation coefficient in a transversely isotropic sample made of phenolic material. Using the spectral-ratio method, we estimate the group (effective) attenuation coefficient of P-waves transmitted through the sample for a wide range of propagation angles (from [Formula: see text] to [Formula: see text]) with the symmetry axis. Correction for the difference between the group and phase angles and for the angular velocity variation help us to obtain the normalized phase attenuation coefficient [Formula: see text] governed by the Thomsen-style attenuation-anisotropy parameters [Formula: see text] and [Formula: see text]. Whereas the symmetry axis of the angle-dependent coefficient [Formula: see text] practically coincides with that of the velocity function, the magnitude of the attenuation anisotropy far exceeds that of the velocity anisotropy. The quality factor [Formula: see text] increases more than tenfold from the symmetry axis (slow direction) to the isotropy plane (fast direction). Inversion of the coefficient [Formula: see text] using the Christoffel equation yields large negative values of the parameters [Formula: see text] and [Formula: see text]. The robustness of our results critically depends on several factors, such as the availability of an accurate anisotropic velocity model and adequacy of the homogeneous concept of wave propagation, as well as the choice of the frequency band. The methodology discussed here can be extended to field measurements of anisotropic attenuation needed for AVO (amplitude-variation-with-offset) analysis, amplitude-preserving migration, and seismic fracture detection.

Processing of converted (PS) waves currently adopted by the exploration industry is essentially based on resorting the PS data into common‐conversion‐point gathers and using them for velocity analysis. Here, we explore an alternative procedure. Our key idea is to generate the so‐called pseudo‐shear (ΨS) seismograms from the recorded PP and PS traces and run conventional velocity analysis on the reconstructed ΨS data. This results in an effective S‐wave velocity model because our method creates data that possess kinematics of pure shear‐wave primaries. We never deal with such complexities of converted waves as moveout asymmetry, reflection point dispersal, and polarity reversal; therefore, these generally troublesome features become irrelevant. We describe the details of our methodology and examine its behavior both analytically and numerically. We apply the developed processing flow to a four‐component ocean‐bottom cable line acquired in the Gulf of Mexico. Since the obtained stacking velocities of P‐ and ΨS‐waves indicate the presence of effective anisotropy, we proceed with estimating a family of kinematically equivalent vertical transversely isotropic (VTI) velocity models of the subsurface.