The intrinsic flexibility of layered double hydroxides (LDHs) has been here exploited to design hybrid multilayered materials by intercalation of the copper phthalocyaninetetrasulfonate (CuPcTs) complex in the interlamellar space offered by these layered hosts through a simple anion-exchange procedure. Taking advantage of their chemical versatility, two different LDHs, the diamagnetic ZnAl and the ferromagnetic NiAl, have been synthesized and characterized to explore the differences in the magnetic properties of the hybrids introduced by the intercalation of the paramagnetic complex.
A novel [70]fulleropyrrolidine functionalized with a nitroxide radical has been synthesized. After pulsed photoexcitation, time-resolved electron paramagnetic resonance (EPR) spectra have been recorded in liquid solution at standard X-band (9.5 GHz) and W-band (95 GHz) microwave frequencies. The spectra exhibit strongly electron spin polarized ground and excited states, the latter being arising from the spin coupling of the nitroxide's electron spin with the fullerene's excited triplet state. The EPR parameters such as g-values and hyperfine coupling constants have been discussed in terms of the spin Hamiltonian for excited doublet, triplet and quartet states. On the basis of the strength of the exchange interaction between the fullerene triplet and the radical group, two, out of a possible four [70]fulleropyrrolidine isomeric monoadducts, have been characterized.
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