A general ultrathin-nanosheet-induced strategy for producing a 3D mesoporous network of Co 3 O 4 is reported. The fabrication process introduces a 3D N-doped carbon network to adsorb metal cobalt ions via dipping process. Then, this carbon matrix serves as the sacrificed template, whose N-doping effect and ultrathin nanosheet features play critical roles for controlling the formation of Co 3 O 4 networks. The obtained material exhibits a 3D interconnected architecture with large specific surface area and abundant mesopores, which is constructed by nanoparticles. Merited by the optimized structure in three length scales of nano particles-mesopores-networks, this Co 3 O 4 nanostructure possesses superior performance as a LIB anode: high capacity (1033 mAh g −1 at 0.1 A g −1 ) and long-life stability (700 cycles at 5 A g −1 ). Moreover, this strategy is verified to be effective for producing other transition metal oxides, including
As a promising bifunctional electrocatalyst for water splitting, NiFe-layered double hydroxide (NiFe LDH) demonstrates an excellent activity toward oxygen evolution reaction (OER) in alkaline solution. However, its hydrogen evolution reaction (HER) activity is challenged owing to the poor electronic conductivity and insufficient electrochemical active sites. Therefore, a three-dimensional self-supporting metal hydroxide/oxide electrode with abundant oxygen vacancies is prepared by electrodepositing CeO nanoparticles on NiFe LDH nanosheets. According to the density functional theory calculations and experimental studies, the oxygen vacancies at the NiFe LDH/CeO interface can be introduced successfully because of the positive charges accumulation resulting from the local electron potential difference between NiFe LDH and CeO . The oxygen vacancies accelerate the electron/ion migration rates, facilitate the charge transfer, and increase the electrochemical active sites, which give rise to an efficient activity toward HER in alkaline solution. Furthermore, NF@NiFe LDH/CeO needs a lower potential of 1.51 V to drive a current density of 10 mA cm in overall water splitting and demonstrates a superior performance compared with the benchmark Pt/C and RuO, which is indicated to be a promising bifunctional electrode catalyst.
Engineering of 3D graphene/metal composites with ultrasmall sized metal and robust metal-graphene interfacial interaction for energy storage application is still a challenge and rarely reported. In this work, a facile top-down strategy is developed for the preparation of SnSb-in-plane nanoconfined 3D N-doped porous graphene networks for sodium ion battery anodes, which are composed of several tens of interconnected empty N-graphene boxes in-plane firmly embedded with ultrasmall SnSb nanocrystals. The all-around encapsulation (plane-to-plane contact) architecture that provides a large interface between N-graphene and SnSb nanocrystal not only effectively enhances the electron conductivity and structural integrity of the overall electrode, but also offers excess interfacial sodium storage, thus leading to much enhanced high-rate sodium storage capacity and stability, which has been proven by both experimental results and first-principles simulations. Moreover, this top-down strategy can enable new paths to the low-cost and high-yield synthesis of 3D graphene/metal composites for applications in energy-related fields and beyond.
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