SUMMARY We derive a theoretical relationship between the cross correlation of ambient Rayleigh waves (seismic ambient noise) and the attenuation parameter α associated with Rayleigh-wave propagation. In particular, we derive a mathematical expression for the multiplicative factor relating normalized cross correlation to the Rayleigh-wave Green’s function. Based on this expression, we formulate an inverse problem to determine α from cross correlations of recorded ambient signal. We conduct a preliminary application of our algorithm to a relatively small instrument array, conveniently deployed on an island. In our setup, the mentioned multiplicative factor has values of about 2.5–3, which, if neglected, could result in a significant underestimate of α. We find that our inferred values of α are reasonable, in comparison with independently obtained estimates found in the literature. Allowing α to vary with respect to frequency results in a reduction of misfit between observed and predicted cross correlations.

SUMMARY We compile a data set of Rayleigh-wave phase velocities between pairs of stations, based on teleseismic events located on the same great circle as the two stations. We validate our observations against dispersion estimates based on ambient-noise cross correlations at the same station pairs. Discrepancies between the results of the two methods can in principle be explained by deviations in the wave propagation path between earthquake and receivers, due to lateral heterogeneity in the Earth’s structure, but the latter effect has, so far, not been precisely quantified nor corrected for. We implement an algorithm to measure the arrival angle of earthquake-generated surface waves and correct the dispersion measurements accordingly. Application to a data set from the Central-Western Mediterranean shows that the arrival-angle correction almost entirely accounts for the discrepancy in question, decreasing significantly the velocity bias for a wide range of periods.

The complex tectonic setting of the central‐western Mediterranean has interested geoscientists for decades, but its geodynamic evolution remains a matter of debate. We rely on 807 seismometers from southern Europe and northern Africa to measure Rayleigh and Love phase velocities in the period range ∼5–200 s, based on teleseismic earthquakes and seismic ambient noise. By nonlinear joint inversion of the phase‐velocity maps, we obtain a 3‐D shear‐wave velocity (VS) model of the study area. At shallow depths, our model correlates with surface geology and reveals the presence of a sedimentary cover in the Liguro‐Provençal basin, as opposed to the Tyrrhenian basin where this is either very thin or absent. At ∼5‐km depth, high velocities below the Magnaghi, Vavilov, and Marsili seamounts point to an exhumed, scarcely serpentinized mantle. These are replaced by lower velocities at larger depths, likely connected to the presence of partial melt. At 50–60‐km depth, a very heterogeneous structure characterizes the Tyrrhenian basin, with low velocities pointing to the presence of fluids due to the lateral mantle inflow from the Ionian slab edges, and higher velocities associated with a relatively dry upper mantle. Such heterogeneity disappears at depths ≳75 km, replaced by more uniform velocities which are ∼2% lower than those found in the Liguro‐Provençal basin. We infer that, at the same depths, the Tyrrhenian basin is characterized by a larger concentration of fluids and possibly higher temperatures.

Colemanite, CaB3O4(OH)3H2O, is the most common hydrous Ca-borate, as well as a major mineral commodity of boron. In this study, we report a thorough chemical analysis and the low-temperature behavior of a natural sample of colemanite, by means of a multi-methodological approach. From the chemical point of view, the investigated sample resulted to be relatively pure, its composition being very close to the ideal one, with only a minor substitution of Sr 2+ for Ca 2+ . At about 270.5 K a displacive phase transition from the centrosymmetric P21/a to the acentric P21 space group occurs.On the basis of in situ single-crystal synchrotron X-ray (down to 104 K) and neutron diffraction (at 20 K) data, the hydrogen-bonding configuration of both the polymorphs and the structural modifications at the atomic scale at varying temperatures are described. The asymmetric distribution of ionic charges along the [010] axis, allowed by the loss of the inversion center, is likely responsible for the reported ferroelectric behavior of colemanite below the phase transition temperature.