Since Horton in 1965, many authors have sought to aggregate different variables characterizing the state of water into a single value called Water Quality Index ( W Q I ). This index is intended to facilitate the operational management of water resources and their allocation for different uses. Detailed and operational description of the main W Q I calculations are here reviewed. The review contains: (1) an historical analysis of the evolution of W Q I calculation methods by looking both at the choice of variables, the methods of weighting and aggregating these variables into a final single value; (2) an illustration of the contradictions observed in the final result when, on the same database, the W Q I is calculated by different methods; (3) the significant progress possible via fuzzy logic to define a W Q I adapted to specific water use.
International audienceNegative self-potential anomalies can be generated at the ground surface by ore bodies and ground water contaminated with organic compounds. These anomalies are connected to the distribution of the redox potential of the ground water. To study the relationship between redox and self-potential anomalies, a controlled sandbox experiment was performed. We used a metallic iron bar inserted in the left-hand side of a thin Plexiglas sandbox filled with a calibrated sand infiltrated by an electrolyte. The self-potential signals were measured at the surface of the tank (at different time lapses) using a pair of non-polarizing electrodes. The self-potential, the redox potential, and the pH were also measured inside the tank on a regular grid at the end of the experiment. The self-potential distribution sampled after six weeks presents a strong negative anomaly in the vicinity of the top part of the iron bar with a peak amplitude of −82 mV. The resulting distributions of the pH, redox, and self-potentials were interpreted in terms of a geobattery model combined with a description of the electrochemical mechanisms and reactions occurring at the surface of the iron bar. The corrosion of iron yields the formation of a resistive crust of fougerite at the surface of the bar. The corrosion modifies both the pH and the redox potential in the vicinity of the iron bar. The distribution of the self-potential is solved with Poisson's equation with a source term given by the divergence of a source current density at the surface of the bar. In turn, this current density is related to the distribution of the redox potential and electrical resistivity in the vicinity of the iron bar. A least-squares inversion method of the self-potential data, using a 2D finite difference simulation of the forward problem, was developed to retrieve the distribution of the redox potential
We here review the extraordinary mineralogical properties of green rusts and their naturally occurring form, fougerite, and discuss the pertinence of these properties within the alkaline hydrothermal vent (AHV) hypothesis for life's emergence. We put forward an extended version of the AHV scenario which enhances the conformity between extant life and its earliest progenitor by extensively making use of fougerite's mechanistic and catalytic particularities.
The flow of ground water in a buried permeable paleo‐channel can be observed at the ground surface through its self‐potential signature. We apply this method to delineate the Saint‐Ferréol paleo‐channel of the Rhone River located in Camargue, in the South East of France. Negative potentials, ∼−30 mV (reference taken outside the paleo‐channel), are associated with ground water flow in this major sand‐filled channel (500 m wide). Electrical resistivity is primarily controls by the salinity of the pore water. Electrical resistivity tomography and in situ sampling show the salinity of the water inside the paleo‐channel is ten times smaller by comparison with the pore water of the surrounding sediments. Combining electrical resistivity surveys, self‐potential data, and a minimum of drilling information, a 3‐D reconstruction of the architecture of the paleo‐channel is obtained showing the usefulness of this methodology for geomorphological reconstructions in this type of coastal environment.
In contaminant plumes or in the case of ore bodies, a source current density is produced at depth in response to the presence of a gradient of the redox potential. Two charge carriers can exist in such a medium: electrons and ions. Two contributions to the source current density are associated with these charge carriers (i) the gradient of the chemical potential of the ionic species and (ii) the gradient of the chemical potential of the electrons (i.e., the gradient of the redox potential). We ran a set of experiments in which a geobattery is generated using electrolysis reactions of a pore water solution containing iron. A DC power supply is used to impose a difference of electrical potential of 3 V between a working platinum electrode (anode) and an auxiliary platinum electrode (cathode). Both electrodes inserted into a tank filled with a well-calibrated sand infiltrated by a (0.01 mol L(-1) KCl+0.0035 mol L(-)(1) FeSO(4)) solution. After the direct current is turned off, we follow the pH, the redox potential, and the self-potential at several time intervals. The self-potential anomalies amount to a few tens of millivolts after the current is turned off and decreases over time. After several days, all the redox-active compounds produced initially by the electrolysis reactions are consumed through chemical reactions and the self-potential anomalies fall to zero. The resulting self-potential anomalies are shown to be much weaker than the self-potential anomalies observed in the presence of an electronic conductor in the laboratory or in the field. In the presence of a biotic or an abiotic electronic conductor, the self-potential anomalies can amount to a few hundred millivolts. These observations point out indirectly the potential role of bacteria forming biofilms in the transfer of electrons through sharp redox potential gradient in contaminant plumes that are rich in organic matter.
In a context of increased land and natural resources scarcity, the possibilities for local authorities and stakeholders of anticipating evolutions or testing the impact of envisaged developments through scenario simulation are new challenges. PRECOS's approach integrates data pertaining to the fields of water and soil resources, agronomy, urbanization, land use and infrastructure etc. It is complemented by a socio-economic and regulatory analysis of the territory illustrating its constraints and stakes. A modular architecture articulates modeling software and spatial and temporal representations tools. It produces indicators in three core domains: soil degradation, water and soil resources and agricultural production. As a territory representative of numerous situations of the Mediterranean Basin (urban pressures, overconsumption of spaces, degradation of the milieus), a demonstration in the Crau's area (Southeast of France) has allowed to validate a prototype of the approach and to test its feasibility in a real life situation. Results on the Crau area have shown that, since the beginning of the 16th century, irrigated grasslands are the cornerstones of the anthropic-system, illustrating how successfully men's multi-secular efforts have maintained a balance between environment and local development. But today the ecosystem services are jeopardized firstly by urban sprawl and secondly by climate change. Pre-diagnosis in regions of Emilia-Romagna (Italy) and Valencia (Spain) show that local end-users and policy-makers are interested by this approach. The modularity of indicator calculations and the availability of geo-databases indicate that PRECOS may be up scaled in other socio-economic contexts.
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