The rheology of NFC suspensions that exhibited different microstructures and colloidal stability, namely TEMPO and enzymatic NFC suspensions, was investigated at the macro and mesoscales using a transparent Couette rheometer combined with optical observations and ultrasonic speckle velocimetry (USV). Both NFC suspensions showed a complex rheology, which was typical of yield stress, non-linear and thixotropic fluids. Hysteresis loops and erratic evolutions of the macroscale shear stress were also observed, thereby suggesting important mesostructural changes and/or inhomogeneous flow conditions. The in situ optical observations revealed drastic mesostructural changes for the enzymatic NFC suspensions, whereas the TEMPO NFC suspensions did not exhibit mesoscale heterogeneities. However, for both suspensions, USV measurements showed that the flow was heterogeneous and exhibited complex situations with the coexistence of multiple flow bands, wall slippage and possibly multidimensional effects. Using USV measurements, we also showed that the fluidization of these suspensions could presumably be attributed to a progressive and spatially heterogeneous transition from a solid-like to a liquid-like behavior. As the shear rate was increased, the multiple coexisting shear bands progressively enlarged and nearly completely spanned over the rheometer gap, whereas the plug-like flow bands were eroded.
In this study, we characterized and modeled the rheology of TEMPO-oxidized cellulose nanofibril (NFC) aqueous suspensions with electrostatically stabilized and unflocculated nanofibrous structures. These colloidal suspensions of slender and wavy nanofibers exhibited a yield stress and a shear thinning behavior at low and high shear rates, respectively. Both the shear yield stress and the consistency of these suspensions were power-law functions of the NFC volume fraction. We developed an original multiscale model for the prediction of the rheology of these suspensions. At the nanoscale, the suspensions were described as concentrated systems where NFCs interacted with the Newtonian suspending fluid through Brownian motion and long range fluid-NFC hydrodynamic interactions, as well as with each other through short range hydrodynamic and repulsive colloidal interaction forces. These forces were estimated using both the experimental results and 3D networks of NFCs that were numerically generated to mimic the nanostructures of NFC suspensions under shear flow. They were in good agreement with theoretical and measured forces for model colloidal systems. The model showed the primary role played by short range hydrodynamic and colloidal interactions on the rheology of NFC suspensions. At low shear rates, the origin of the yield stress of NFC suspensions was attributed to the combined contribution of repulsive colloidal interactions and the topology of the entangled NFC networks in the suspensions. At high shear rates, both concurrent colloidal and short (in some cases long) range hydrodynamic interactions could be at the origin of the shear thinning behavior of NFC suspensions.
This paper focuses on the study of the physical, biochemical, structural, and thermal properties of plant fibres of Rhecktophyllum camerunense (RC), Neuropeltis acuminatas (NA) and Ananas comosus (AC) from the equatorial region of Cameroon. The traditional use of these fibres inspired researchers to investigated their properties. This study aims at improving the state of knowledge with a view to diversifying applications. The fibres are extracted by retting. Then, their apparent density was measured following the ASTM D792 standard and their water moisture absorption and moisture content were also evaluated. Their molecular structure was studied by ATR-FTIR spectroscopy. A quantitative analysis of the biochemical composition was performed according to the analytical technique for the pulp and paper industry (TAPPI). A TGA/DSC analysis was also performed. The results reveal that the AC, NA and RC fibres have densities of 1.26 ± 1.06, 0.846 ± 0.13 and 0.757 ± 0.08 g•cm −3 respectively. They are also hydrophilic with a water absorption rate of 188.64 ± 11.94%, 276.16% ± 8.07% and 198.17% ± 20%. They have a moisture content of 12.21%, 10.36% and 9.37%. The studied fibres exhibit functional groups that are related to the presence of hemicellulose, pectin, lignin and cellulose. The cellulose crystallinity index was found to be 67.99%, 46.5% and 59.72% respectively. The fibres under study have the following chemical composition: an extractive content of 3.07%, 14.77% and 8.74%; a pectin content of 4.15%, 7.69% and 3.45%; a hemicellulose content of 4.90%, 15.
SignificanceWhile most attention has so far been devoted to the tensile properties of crystalline cellulose, the main elementary building block of plants, we show here using atomistic simulations that their shear is also an important mode of deformation, occurring at stress levels lower than tension with much larger ductility. We also demonstrate how crystalline defects like dislocations drastically facilitate plasticity. This analysis can be used as a basis for the micromechanical modeling of cellulose microfibrils that are currently considered as promising eco-friendly alternatives to synthetic fibers for structural materials.
Nanocelluloses (cellulose nanocrystals, CNCs, or cellulose nanofibrils, CNFs) are the elementary reinforcing constituents of plant cell walls. Because of their pronounced slenderness and outstanding intrinsic mechanical properties, nanocelluloses constitute promising building blocks for the design of future biobased high-performance materials such as nanocomposites, dense and transparent films, continuous filaments, and aerogels and foams. The research interest in nanocellulose-based aerogels and foams is recent but growing rapidly. These materials have great potential in many engineering fields, including construction, transportation, energy, and biomedical sectors. Among the various processing routes used to obtain these materials, ice-templating is one of the most regarded, owing to its simplicity and versatility and the wide variety of porous materials that this technique can provide. The focus of this review is to discuss the current state of the art and understanding of ice-templated porous nanocellulose-based materials. We provide a review of the main forming processes that use the principle of ice-templating to produce porous nanocellulose-based materials and discuss the effect of processing conditions and suspension formulation on the resulting microstructures of the materials.
The elastic properties of cellulose nanofibril (NFC) nanocomposites and nanopapers are predicted by a multiscale network model that shows that the deformation mechanisms are governed by the bonds between rigid NFC segments and in the kinked regions.
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