ADE SCHULTEN 1 published a crystallographic and optical in-. vestigation of the bismuth oxyhalides in 1900. He succeeded in preparing minute square plates capped with pyramidal planes, but evidently the difficulties of manipulation prevented the measurement of interracial angles. He did, however, record a negative uniaxial figure observed in a direction perpendicular to the plane of the square plates of all three salts BiOC1, BiOBr, and BiOI. The present work was undertaken to extend A. de Schulten's observations, to measure the axial ratios, and to determine the crystal-structure.It was desirable to obtain single crystals sufficiently large to mount for goniometric and X-ray work. This was finally achieved by a diffusion method. A concentrated solution of bismuth chloride in hydrochloric acid was poured into a small crystallizing dish, and then, disturbing as little as possible the contents of the dish, layers of hydrochloric acid of diminishing concentration were slowly added. The dish was then filled to the top with water and a surrounding larger dish also completely filled with water. The larger dish was then covered with a glass plate and left undisturbed at a constant temperature of about 18 ~ C. for three days. Prolonging the duration of the experiment did not produce larger crystals, but sometimes a 1 A. de Schulten, Bull. Soc. Chim. Faris, 1900, vol. 23, p. 156. E
SummaryCorrelated data prove the approximate constancy of the number of oxygen atoms in the unit cells of several nepheline and elaeolite specimens. Thence the number of atoms of each kind per unit cell have been counted. The cell-volumes and optical properties have slso been correlated with the chemical composition. An approximate structure is suggested which, together with the chemical work, explains the variable composition of nepheline. The contents of the unit cell may be written Si16−nAln(Na,K,½Ca)n where n ranges from 6.6 to 8.2. Kaliophilite is shown to possess a much larger cell than that of nepheline, and its Lauegram exhibits higher symmetry. 'Pseudonepheline' (rich in potassium) has a slightly greater cell-volume than normal nepheline, but its Lauegram is almost identical and its axial ratio only slightly less.
Nevil Story-Maskelyne described in 1870 the mineral constituents of the Bustee meteorite, which was observed to fall in 1852 near Bustee about 45 miles west of Goruckpur, India. The stone, weighing 1429 grams, now preserved in the British Museum collections, was found to consist chiefly of enstatite and diopside, and two constituents proved to be new minerals. Pale, chestnut-brown spherules of calcium sulphide, CaS, Story-Maskelyne named oldhamite and golden-yellow octahedra found embedded chiefly in the oldhamite he named osbornite. One side of the meteorite has been ground to reveal the nodules of oldhamite and a coloured lithograph in W. Flight's book ‘A chapter in the history of meteorites’ reproduces the appearance of the chief mineral constituents very well. The minute octahedra of osbornite are easily visible with a lens in the meteorite itself.
Concentrates from the platiniferous norites of the Bushveld, Transvaal, are not completely soluble in aqua regia. The insoluble portion consists of steel-grey fragments first analysed chemically by R. A. Cooper and considered by him to be a new platinum mineral represented by the formula Pt(As,S)2. The name cooperite was proposed for the new mineral by F. Wartenweiller, and after further work Cooper decided that the arsenic found in the early analysis was due to the presence of sperrylite, and he changed the formula to PtS2. H. Schneiderhöhn observed simple twinning and, less frequently, polysynthetie lamellae on polished sections of mineral grains from the same deposits, and he suggested that cooperite is probably orthorhombic and isomorphous with marcasite. The latest account of the new mineral has been published by H. R. Adam who gave several analyses of cooperite from the Rustenburg and Potgietersrust districts and concluded that the ‘mineral is PtS2 with a small amount of excess metal (platinum, palladium, and nickel) present in solid solution’.
The discovery of nigerite, a new tin-bearing mineral, by R. Jacobson and J. S. Webb claims more than the passing interest of an addition to the few known species containing appreciable tin. Nigerite is the first mineral to be discovered in which both tin and aluminium are essential constituents. Its chief interest to mineralogists lies in its close relationship to minerals like spinel and corundum based on a close-packed or nearly close-packed assemblage of oxygen ions.Samples of nigerite submitted to us for investigation consist of brittle, lustrous, brown, weakly magnetic, hexagonal plates up to 5 x 2 mm. in size but mostly much smaller. These samples also contained grains of cassiterite, columbite, gahnite, sillimanite, quartz, andalusite, and chrysoberyl, which were easily separated by hand-picking.
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