The composition of the neutral gas comas of most comets is dominated by H2O, CO and CO2, typically comprising as much as 95 per cent of the total gas density. In addition, cometary comas have been found to contain a rich array of other molecules, including sulfuric compounds and complex hydrocarbons. Molecular oxygen (O2), however, despite its detection on other icy bodies such as the moons of Jupiter and Saturn, has remained undetected in cometary comas. Here we report in situ measurement of O2 in the coma of comet 67P/Churyumov-Gerasimenko, with local abundances ranging from one per cent to ten per cent relative to H2O and with a mean value of 3.80 ± 0.85 per cent. Our observations indicate that the O2/H2O ratio is isotropic in the coma and does not change systematically with heliocentric distance. This suggests that primordial O2 was incorporated into the nucleus during the comet's formation, which is unexpected given the low upper limits from remote sensing observations. Current Solar System formation models do not predict conditions that would allow this to occur.

Abstract. We present a survey of the formaldehyde emission in a sample of eight Class 0 protostars obtained with the IRAM and JCMT millimeter telescopes. The range of energies of the observed transitions allows us to probe the physical and chemical conditions across the protostellar envelopes. The data have been analyzed with three different methods with increasing level of sophistication. We first analyze the observed emission in the LTE approximation, and derive rotational temperatures between 11 and 40 K, and column densities between 1 and 20 × 10 13 cm −2 . Second, we use a LVG code and derive higher kinetic temperatures, between 30 and 90 K, consistent with subthermally populated levels and densities from 1 to 6 × 10 5 cm −3 . The column densities from the LVG modeling are within a factor of 10 with respect to those derived in the LTE approximation. Finally, we analyze the observations based upon detailed models for the envelopes surrounding the protostars, using temperature and density profiles previously derived from continuum observations. We approximate the formaldehyde abundance across the envelope with a jump function, the jump occurring when the dust temperature reaches 100 K, the evaporation temperature of the grain mantles. The observed formaldehyde emission is well reproduced only if there is a jump of more than two orders of magnitude, in four sources. In the remaining four sources the data are consistent with a formaldehyde abundance jump, but the evidence is more marginal (≤2 σ). The inferred inner H 2 CO abundance varies between 1 × 10 −8 and 6 × 10 −6 . The absolute values of the jump in the H 2 CO abundance are uncertain by about one order of magnitude, because of the uncertainties in the density, ortho to para ratio, temperature and velocity profiles of the inner region, as well as the evaporation temperature of the ices. We discuss the implications of these jumps for our understanding of the origin and evolution of ices in low mass star forming regions. Finally, we give predictions for the submillimeter H 2 CO lines, which are particularly sensitive to the abundance jumps.

Abstract. We present IRAM 30 m and JCMT observations of HDO lines towards the solar-type protostar IRAS 16293−2422. Five HDO transitions have been detected on-source, and two were unfruitfully searched for towards a bright spot of the outflow of IRAS 16293−2422. We interpret the data by means of the Ceccarelli et al. (1996) model, and derive the HDO abundance in the warm inner and cold outer parts of the envelope. The emission is well explained by a jump model, with an inner abundance x HDO in = 1 × 10 −7 and an outer abundance x HDO out ≤ 1 × 10 −9 (3σ). This result is in favor of HDO enhancement due to ice evaporation from the grains in the inner envelope. The deuteration ratio HDO/H 2 O is found to be f in = 3% and f out ≤ 0.2% (3σ) in the inner and outer envelope respectively and therefore, the fractionation also undergoes a jump in the inner part of the envelope. These results are consistent with the formation of water in the gas phase during the cold prestellar core phase and storage of the molecules on the grains, but do not explain why observations of H 2 O ices consistently derive a H 2 O ice abundance of several 10 −5 to 10 −4 , some two orders of magnitude larger than the gas phase abundance of water in the hot core around IRAS 16293−2422.

We present the Early Release Observations of the HH 46/47 system and HH 46 IRS 1 source, taken with the three instruments aboard the Spitzer Space Telescope. The optically invisible southwest lobe, driven by the HH 47C bow shock, is revealed in full detail by the Infrared Array Camera (IRAC) images and displays a ''loop''-like morphology. Both of the mid-infrared outflow lobes are narrower than those of CO flow. We believe that the combination of emission by H 2 rotational lines [S(11)-S(4)] and some atomic lines, which fall within the IRAC passbands, are responsible for the bulk of the observed emission, although contributions from the 3.3, 6.2, and 7.7 m polycyclic aromatic hydrocarbon emission bands cannot be ruled out. Weak spectral features corresponding to these emitters are present in the Infrared Spectrograph spectrum of the HH 47A bow shock. The spectrum of HH 46 IRS 1 shows remarkable similarities to those of high-mass protostars, which include the presence of H 2 O, CO 2 , CH 4 , and possibly NH 3 , CH 3 OH, and NH þ 4 ices. The high ice abundances and the lack of signs of thermal processing indicate that these ices in the envelope are well shielded from the powerful outflow and its cavity. Emission from the Bok globule at 24 m is detected and displays a similar structure to that observed at 8 m.

Abstract. We revisit the reported detection and upper limits on HDO in ice mantles present in the molecular cloud environments of the massive young protostars Gl 2136 and W33 A, using independent VLT-ISAAC and UKIRT-CGS4 spectroscopic observations. We also present VLT and UKIRT spectra of RAFGL 7009 near the HDO absorption wavelength and reanalyze the ISO-SWS spectral data for NGC 7538 IRS9, Orion-BN and S140. We demonstrate that the previously reported detections of HDO in W33 A and NGC 7538 IRS9 are incorrect. We present an in-depth analysis that shows that, besides the sensitivity limits, detection of low levels of HDO is difficult in amorphous ice mantles when features from solid methanol, a common grain mantle constituent, are present. We discuss the specific problems arising in the ISO data in this wavelength range for NGC 7538 IRS9. Using VLT-ISAAC observations, we also investigate the HDO/H 2 O ratio toward the intermediate mass stars IRAS 05329-0728 and IRAS 08448-4343. Our derived upper limits for the D/H ratio in water ice range from HDO/H 2 O < 1% to 0.2% in the different sources, and we discuss these limits in comparison with values derived in other environments.

Context. Apart from being an important coolant, water is known to be a tracer of high-velocity molecular gas. Recent models predict relatively high abundances behind interstellar shockwaves. The dynamical and physical conditions of the water emitting gas, however, are not fully understood yet. Using the Herschel Space Observatory, it is now possible to observe water emission from supersonic molecular outflows at high spectral and spatial resolution. Several molecular outflows from young stars are currently being observed as part of the WISH (Water In Star-forming regions with Herschel) key program. Aims. We aim to determine the abundance and distribution of water, its kinematics, and the physical conditions of the gas responsible for the water emission. The observed line profile shapes help us understand the dynamics in molecular outflows. Methods. We mapped the VLA 1623 outflow, in the ground-state transitions of o-H 2 O, with the HIFI and PACS instruments. We also present observations of higher energy transitions of o-H 2 O and p-H 2 O obtained with HIFI and PACS towards selected outflow positions. From comparison with non-LTE radiative transfer calculations, we estimate the physical parameters of the water emitting regions. Results. The observed water emission line profiles vary over the mapped area. Spectral features and components, tracing gas in different excitation conditions, allow us to constrain the density and temperature of the gas. The water emission originates in a region where temperatures are comparable to that of the warm H 2 gas (T > ∼ 200 K). Thus, the water emission traces a gas component significantly warmer than the gas responsible for the low-J CO emission. The water column densities at the CO peak positions are low, i.e. N(H 2 O) (0.03−10) × 10 14 cm −2 . Conclusions. The water abundance with respect to H 2 in the extended outflow is estimated at X(H 2 O) < 1 × 10 −6 , significantly lower than what would be expected from most recent shock models. The H 2 O emission traces a gas component moving at relatively high velocity compared to the low-J CO emitting gas. However, other dynamical quantities such as the momentum rate, energy, and mechanical luminosity are estimated to be the same, independent of the molecular tracer used, CO or H 2 O.

We analyze the submillimeter emission surrounding the new FU Orionis-type object, HBC 722. We present the first epoch of observations of the active environs of HBC 722, with imaging and spectroscopy from PACS, SPIRE, and HIFI aboard the Herschel Space Observatory, as well as CO J= 2-1 and 350 µm imaging (SHARC-II) with the Caltech Submillimeter Observatory. The primary source of submillimeter continuum emission in the region -2MASS 20581767+4353310 -is located 16 ′′ south-southeast of the optical flaring source while the optical and near-IR emission is dominated by HBC 722. A bipolar outflow extends over HBC 722; the most likely driver is the submillimeter source. We detect warm

Context. The chemical inventory of planets is determined by the physical and chemical processes that govern the early phases of star formation. Nitrogen-bearing species are of interest as many provide crucial precursors in the formation of life-related matter. Aims. The aim is to investigate nitrogen-bearing complex organic molecules towards two deeply embedded Class 0 low-mass protostars (Perseus B1-c and Serpens S68N) at millimetre wavelengths with the Atacama Large Millimeter/submillimeter Array (ALMA). Next, the results of the detected nitrogen-bearing species are compared with those of oxygen-bearing species for the same and other sources. The similarities and differences are used as further input to investigate the underlying formation pathways. Methods. ALMA observations of B1-c and S68N in Band 6 (~1 mm) and Band 5 (~2 mm) are studied at ~0.5′′ resolution, complemented by Band 3 (~3 mm) data in a ~2.5′′ beam. The spectra are analysed for nitrogen-bearing species using the CASSIS spectral analysis tool, and the column densities and excitation temperatures are determined. A toy model is developed to investigate the effect of source structure on the molecular emission. Results. Formamide (NH2CHO), ethyl cyanide (C2H5CN), isocyanic acid (HNCO, HN13CO, DNCO), and methyl cyanide (CH3CN, CH2DCN, and CHD2CN) are identified towards the investigated sources. Their abundances relative to CH3OH and HNCO are similar for the two sources, with column densities that are typically an order of magnitude lower than those of oxygen-bearing species. The largest variations, of an order of magnitude, are seen for NH2CHO abundance ratios with respect to HNCO and CH3OH and do not correlate with the protostellar luminosity. In addition, within uncertainties, the nitrogen-bearing species have similar excitation temperatures to those of oxygen-bearing species (~100–300 K). The measured excitation temperatures are larger than the sublimation temperatures for the respective species. Conclusions. The similarity of most abundances with respect to HNCO for the investigated sources, including those of CH2DCN and CHD2CN, hints at a shared chemical history, especially the high D-to-H ratio in cold regions prior to star formation. However, some of the variations in abundances may reflect the sensitivity of the chemistry to local conditions such as temperature (e.g. NH2CHO), while others may arise from differences in the emitting areas of the molecules linked to their different binding energies in the ice. The excitation temperatures likely reflect the mass-weighted kinetic temperature of a gas that follows a power law structure. The two sources discussed in this work add to the small number of sources that have been subjected to such a detailed chemical analysis on Solar System scales. Future data from the James Webb Space Telescope will allow a direct comparison between the ice and gas abundances of both smaller and larger nitrogen-bearing species.