Poland, being the 3rd largest and growing producer of mushrooms in the world, generates almost 25% of the total European production. The generation rate of waste mushroom spent compost (MSC) amounts to 5 kg per 1 kg of mushrooms produced. We proposed the MSC treatment via torrefaction for the production of solid fuel—biocoal. In this research, we examined the MSC torrefaction kinetics using thermogravimetric analyses (TGA) and we tested the influence of torrefaction temperature within the range from 200 to 300 °C and treatment time lasting from 20 to 60 min on the resulting biocoal’s (fuel) properties. The estimated value of the torrefaction activation energy of MSC was 22.3 kJ mol−1. The highest calorific value = 17.9 MJ kg−1 d.m. was found for 280 °C (60 min torrefaction time). A significant (p < 0.05) influence of torrefaction temperature on HHV increase within the same group of torrefaction duration, i.e., 20, 40, or 60 min, was observed. The torrefaction duration significantly (p < 0.05) increased the HHV for 220 °C and decreased HHV for 300 °C. The highest mass yield (98.5%) was found for 220 °C (60 min), while the highest energy yield was found for 280 °C (60 min). In addition, estimations of the biocoal recirculation rate to maintain the heat self-sufficiency of MSC torrefaction were made. The net quantity of biocoal (torrefied MSC; 65.3% moisture content) and the 280 °C (60 min) torrefaction variant was used. The initial mass and energy balance showed that MSC torrefaction might be feasible and self-sufficient for heat when ~43.6% of produced biocoal is recirculated to supply the heat for torrefaction. Thus, we have shown a concept for an alternative utilization of abundant biowaste (MSC). This research provides a basis for alternative use of an abundant biowaste and can help charting improved, sustainable mushroom production.
New technologies to valorize refuse-derived fuels (RDFs) will be required in the near future due to emerging trends of (1) the cement industry’s demands for high-quality alternative fuels and (2) the decreasing calorific value of the fuels derived from municipal solid waste (MSW) and currently used in cement/incineration plants. Low-temperature pyrolysis can increase the calorific value of processed material, leading to the production of value-added carbonized solid fuel (CSF). This dataset summarizes the key properties of MSW-derived CSF. Pyrolysis experiments were completed using eight types of organic waste and their two RDF mixtures. Organic waste represented common morphological groups of MSW, i.e., cartons, fabrics, kitchen waste, paper, plastic, rubber, PAP/AL/PE composite packaging (multi-material packaging also known as Tetra Pak cartons), and wood. The pyrolysis was conducted at temperatures ranging from 300 to 500 °C (20 °C intervals), with a retention (process) time of 20 to 60 min (20 min intervals). The mass yield, energy densification ratio, and energy yield were determined to characterize the pyrolysis process efficiency. The raw materials and produced CSF were tested with proximate analyses (moisture content, organic matter content, ash content, and combustible part content) and with ultimate analyses (elemental composition C, H, N, S) and high heating value (HHV). Additionally, differential scanning calorimetry (DSC) and thermogravimetric analyses (TGA) of the pyrolysis process were performed. The dataset documents the changes in fuel properties of RDF resulting from low-temperature pyrolysis as a function of the pyrolysis conditions and feedstock type. The greatest HHV improvements were observed for fabrics (up to 65%), PAP/AL/PE composite packaging (up to 56%), and wood (up to 46%).
In work, data from carbonization of the eight main municipal solid waste components (carton, fabric, kitchen waste, paper, plastic, rubber, paper/aluminum/polyethylene (PAP/AL/PE) composite packaging pack, wood) carbonized at 300–500 °C for 20–60 min were used to build regression models to predict the biochar properties (proximate and ultimate analysis) for particular components. These models were then combined in general models that predict the properties of char made from mixed waste components depending on pyrolysis temperature, residence time, and share of municipal solid waste components. Next, the general models were compared with experimental data (two mixtures made from the above-mentioned components carbonized at the same conditions). The comparison showed that most of the proposed general models had a determination coefficient (R2) over 0.6, and the best prediction was found for the prediction of biochar mass yield (R2 = 0.9). All models were implemented into a spreadsheet to provide a simple tool to determine the potential of carbonization of municipal solid waste/refuse solid fuel based on a local mix of major components.
Mushroom production in Poland is an important and dynamically developing element of 12 diverse agriculture. Mushroom spent compost (MSC) is major waste generated during production, 13 i.e., MSC: mushrooms is ~5:1. To date, the main use of MSC is soil application as organic fertilizer.14 To date, several methods of MSC treatment have been researched and developed including 15 production of compost, bioethanol, biogas, enzyme lactase, xylo-saccharides, and hydrogen. 16Torrefaction may be considered a novel approach for biomass valorization. Thus, we are pioneering 17 the potential use of MSC valorization via torrefaction. We explored valorizing the waste biomass of 18 MSC via thermal treatment -torrefaction ('roasting') to produce biochar with improved fuel 19 properties. Here for the first time, we examined and summarized the MSC torrefaction 20 thermogravimetric analyses, fuel properties data of raw biomass of MSC and biochars generated 21 from MSC via torrefaction. The effects of torrefaction temperature (200~300 °C), process time (20~60 22 min), on fuel properties of the resulting biochars were summarized. The dataset contains results of 23 thermogravimetric analysis (TGA) as well as proximate analyses of MSC and generated biochars. 24The presented data are useful in determining MSC torrefaction reaction kinetics, activation energy 25 and to further techno-economical modeling of the feasibility of MSC valorization via torrefaction. 26MSC torrefaction could be exploited as part of valorization resulting from a synergy between an 27 intensive mushroom production with the efficient production of high-quality renewable fuel.
In this study, 12 organic waste materials were subjected to TG/DTG thermogravimetric analysis and DSC calorimetric analysis. These analyses provided basic information about thermochemical transformations and degradation rates during organic waste pyrolysis. Organic waste materials were divided into six basic groups as follows: paper, cardboard, textiles, plastics, hygiene waste, and biodegradable waste. For each group, two waste materials were selected to be studied. Research materials were (i) paper (receipts, cotton wool); (ii) cardboard (cardboard, egg carton); (iii) textiles (cotton, leather); (iv) plastics (polyethylene (PET), polyurethane (PU)); (v) hygiene waste (diapers, leno); and (vi) biodegradable waste (chicken meat, potato peel). Waste materials were chosen to represent the most abundant waste that can be found in the municipal solid waste stream. Based on TG results, kinetic parameters according to the Coats–Redfern method were determined. The pyrolysis activation energy was the highest for cotton, 134.5 kJ × (mol∙K)−1, and the lowest for leather, 25.2 kJ × (mol∙K)−1. The DSC analysis showed that a number of transformations occurred during pyrolysis for each material. For each transformation, the normalized energy required for transformation, or released during transformation, was determined, and then summarized to present the energy balance. The study found that the energy balance was negative for only three waste materials—PET (−220.1 J × g−1), leather (−66.8 J × g−1), and chicken meat (−130.3 J × g−1)—whereas the highest positive balance value was found for potato peelings (367.8 J × g−1). The obtained results may be applied for the modelling of energy and mass balance of municipal solid waste pyrolysis.
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