We demonstrate in this paper the feasibility to elaborate rare-earth free permanent magnets based on cobalt nanorods assemblies with energy product (BH)max exceeding 150 kJ m(-3). The cobalt rods were prepared by the polyol process and assembled from wet suspensions under a magnetic field. Magnetization loops of dense assemblies with remanence to a saturation of 0.99 and squareness of 0.96 were measured. The almost perfect M(H) loop squareness together with electron microscopy and small angle neutron scattering demonstrate the excellent alignment of the rods within the assemblies. The magnetic volume fraction was carefully measured by coupling magnetic and thermogravimetric analysis and found in the range from 45 to 55%, depending on the rod diameter and the alignment procedure. This allowed a quantitative assessment of the (BH)max values. The highest (BH)max of 165 kJ m(-3) was obtained for a sample combining a high magnetic volume fraction and a very large M(H) loop squareness. This study shows that this bottom-up approach is very promising to get new hard magnetic materials that can compete in the permanent magnet panorama and fill the gap between the ferrites and the NdFeB magnets.
The diameter dependence of the coercivity of cobalt nanowires is quantitatively described by micromagnetic modelling, which reveals that the magnetization reversal is driven by nucleation at the edges or at stacking faults.
Abstract:In recent years, persuasive interventions for inducing sustainable mobility behaviours have become an active research field. This review paper systematically analyses existing approaches and prototype systems as well as field studies and describes and classifies the persuasive strategies used for changing behaviours in the domain of mobility and transport. We provide a review of 44 papers on persuasive technology for sustainable transportation aiming to (i) answer important questions regarding the effectiveness of persuasive technology for changing mobility behaviours, (ii) summarize and highlight trends in the technology design, research methods, strategies and theories, (iii) uncover limitations of existing approaches and applications, and (iv) suggest directions for future research.
A positive pANCA test in Greek patients has a diagnostic value in confirming a diagnosis of UC. Measurement of pANCA and ASCA together has a rather limited value in the differential diagnosis between UC and CD but may be of help in studying disease heterogeneity.
Rare-earth free permanent magnets were produced by consolidation of cobalt nanorods synthesized by the polyol process exhibiting a mean diameter in the range 10 to 30 nm. Compactions of magnetically prealigned rod assemblies at various pressures and temperatures were carried out to make dense materials. Bulk magnets exhibiting a very good mechanical strength and an energy product as high as 65 kJ.m-3 were obtained. The best results were obtained when the compaction conditions were soft enough to preserve the morphology and alignment of the rods in the final material, as revealed by X-ray diffraction and neutron scattering. For the first time the bottom-up approach is convincingly reported to produce bulk magnets without the addition of any matrix, the obtained nanostructured materials exhibit coercivity much higher than the AlNiCo magnets and can fill the performance "gap" between hexaferrites and rare-earth based magnets.
Rendering transport behaviours more sustainable is a pressing issue of our times. In this paper, we rely on the deep penetration of mobile phones in order to influence citizens' behavior through data-driven mobility and persuasive profiles. Our proposed approach aims to nudge users on a personalized level in order to change their mobility behavior and make more sustainable choices. To achieve our goal, first we leverage pervasive mobile sensing to uncover users' mobility patterns and use of transportation modes. Second, we construct users' persuadability profiles by considering their personality and mobility behavior. With the use of the aforementioned information we generate personalized interventions that nudge users to adopt sustainable transportation habits. These interventions rely on persuasive technologies and are embedded in a route planning application for smartphones. A pilot study with 30 participants using the system for 6 weeks provided fairly positive evaluation results in terms of the acceptance of our approach and revealed instances of behavioural change.
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