Nanofibrous materials produced through electrospinning are characterized by a high porosity, large specific surface area, and high pore interconnectivity and, therefore, show potential for, e.g., separation and filtration. The development of more inert nanofibers with higher thermal and chemical resistance extends the application field to high-end purification. Silica nanofibrous membranes produced by direct electrospinning of a sol-gel solution without a sacrificing carrier, starting from tetraethoxysilane, meet these challenging requirements. After electrospinning the membrane is highly hydrophobic. Storage under dry conditions preserves this property. Oppositely, a superhydrophilic membrane is obtained by storage under high humidity (month scale). This switch is caused by the reaction of ethoxy groups, present due to incomplete hydrolysis of the precursor, with moisture in the air, resulting in an increased amount of silanol groups. This transition can be accelerated to hour scale by applying a heat treatment, with the additional increase in cross-linking density for temperatures above 400 °C, enabling applications that make use of hydrophobic and hydrophilic membranes by tuning the functionalization. It is showcased that upon designing the water repellent or absorbing nature of the silica material, fast gravity-driven membrane separation of heterogeneous azeotropes can be achieved.
A challenge for the photodegradation of (organic) micro-pollutants in waste water treatment is the mechanistic and kinetic understanding beyond the degradation of the initial (parent) harmful product, e.g. the phenylurea herbicide isoproturon (IPU). By combining liquid chromatography mass spectrometry and kinetic Monte Carlo modeling, we demonstrate that upon optimizing the dip-coating conditions (0.34 mol L -1 TiO2 solution at a coating speed of 160 mm min -1 ) for the functionalization of a superhydrophilic electrospun silica nanofibrous membrane (i) hydroxylation is a dominant reaction pathway and (ii) once IPU reacts on the surface of the TiO2 nanoparticles, further hydroxylation occurs sufficiently fast, with complete IPU removal under the detection limit (5-10 mg Lsolution -1 ) as a result of UV irradiation within 8 hours. As hydroxylation is dominant, degradation intermediates with a higher water solubility are formed and therefore a decreased toxicity is obtained upon reintroducing the treated solution into the environment. This is confirmed by respirometry, with an increase in the oxygen uptake rate of an activated sludge from 5.9 mg O2 gactivated sludge -1 h -1 for an untreated 10 mg L -1 IPU solution to 8.2 mg O2 gactivated sludge -1 h -1 for a solution irradiated for 8 hours, in line with a blank solution.
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