Wearable gas sensors have received lots of attention for diagnostic and monitoring applications, and two-dimensional (2D) materials can provide a promising platform for fabricating gas sensors that can operate at room temperature. In the present study, the room temperature gas-sensing performance of TiCT nanosheets was investigated. 2D TiCT (MXene) sheets were synthesized by removal of Al atoms from TiAlC (MAX phases) and were integrated on flexible polyimide platforms with a simple solution casting method. The TiCT sensors successfully measured ethanol, methanol, acetone, and ammonia gas at room temperature and showed a p-type sensing behavior. The fabricated sensors showed their highest and lowest response toward ammonia and acetone gas, respectively. The limit of detection of acetone gas was theoretically calculated to be about 9.27 ppm, presenting better performance compared to other 2D material-based sensors. The sensing mechanism was proposed in terms of the interactions between the majority charge carriers of TiCT and gas species.
Two-dimensional
(2D) nanomaterials have demonstrated great potential
in the field of gas sensing due to their layered structures. Especially
for 2D transition metal dichalcogenides (TMDs), inherent high surface
areas and their unique semiconducting properties with tunable band
gaps make them compelling for sensing applications. In combination
with the general benefits of 2D nanomaterials, the incorporation of
metal oxides into 2D TMDs is a recent approach for improving the gas
sensing performance of these materials by the synergistic effects
of the hybridization. This Review aims to comprehend the sensing
mechanisms and the synergistic effects of various hybridizations of
2D TMDs and metal oxides. The Review begins with the gas sensing mechanisms
and synthesis methods of 2D TMDs. Achievements in recent research
on 2D TMDs and their metal oxide hybrids for sensor applications are
then comprehensively compiled. To clearly understand the collective
benefits of TMDs and metal oxide hybrids, the hybridization effects
are discussed in three aspects: geometrical, electronic, and chemical
effects.
The sensitive detection of explosive and flammable gases is an extremely important safety consideration in today's industry. Identification of trace amounts of nonpolar analytes at ambient temperatures, however, is still a challenge because of their weak adsorption, and very few studies have been able to achieve it via a chemiresistive mechanism. Herein, we demonstrate the high performance of 2D vanadium carbide MXene (V 2 CT x ) gas sensors with ultrahigh sensitivity toward nonpolar gases. The fabricated 2D V 2 CT x sensor devices consisting of single-/few-layer 2D V 2 CT x on polyimide film were able to detect both polar and nonpolar chemical species including hydrogen and methane with a very low limit of detection of 2 and 25 ppm, respectively, at room temperature (23 °C). The performance of the fabricated V 2 CT x gas sensors in detection of nonpolar gases surpasses that of previously reported state-of-the-art gas sensors based on other 2D materials.
Brain‒machine interface (BMI) is a promising technology that looks set to contribute to the development of artificial limbs and new input devices by integrating various recent technological advances, including neural electrodes, wireless communication, signal analysis, and robot control. Neural electrodes are a key technological component of BMI, as they can record the rapid and numerous signals emitted by neurons. To receive stable, consistent, and accurate signals, electrodes are designed in accordance with various templates using diverse materials. With the development of microelectromechanical systems (MEMS) technology, electrodes have become more integrated, and their performance has gradually evolved through surface modification and advances in biotechnology. In this paper, we review the development of the extracellular/intracellular type of in vitro microelectrode array (MEA) to investigate neural interface technology and the penetrating/surface (non-penetrating) type of in vivo electrodes. We briefly examine the history and study the recently developed shapes and various uses of the electrode. Also, electrode materials and surface modification techniques are reviewed to measure high-quality neural signals that can be used in BMI.
This review focuses on newly emerging two-dimensional MXenes for gas sensing applications from a theoretical to an experimental view to guide future research. Various synthesis routes of 2D MXenes have been explored and recent success of various MXenes has allowed more knowledge on the relations between their structure and materials properties. We review distinctive gas sensing properties of MXenes in two aspects of theoretical and experimental view. Theoretical insight into the gas-surface interaction mechanism and experimental results of various MXenes on their sensing properties are complied and discussed. To tailor and enhance the sensing performance of MXenes, the parameters such as precursors, morphology, surface terminations, and interlayer structures are emphasized. Perspectives on challenges and opportunities are offered for further development of MXenes-based gas sensors.
Therapeutic viruses: A filament‐shaped artificial virus is formed by using a preorganized supramolecular nanoribbon as a template. The artificial virus (see picture), which is composed of the nanoribbon, small interfering RNAs (blue, double‐helix shape), and hydrophobic guests (red), is highly efficient in delivering genes and drugs to the inside of cells.
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