In rural areas without centralized water supply systems, inhabitants often use groundwater of unknown quality as drinking water, without understanding the possible negative consequences on their health. Karstic spring waters from Dobrogea region in Romania were assessed for their potential to be used as drinking water source, according to their quality and seasonal variation. The physico-chemical parameters of waters were compared with the guideline values for drinking water established by the World Health Organization and the Directive 98/83/EC. The nitrate and Cr concentrations exceeded the guideline value in the springs from Southern Dobrogea, but met the quality criteria in those from Northern Dobrogea, thus, to be used as drinking water, the karstic springs located in Southern Dobrogea require treatment for nitrates removal. Heavy metals pollution indices showed low to medium cumulative heavy metal pollution in all springs, while the human health risk assessment by oral exposure indicated possible noncarcinogenic risks of nitrates, both for adults and children in springs from South Dobrogea. A rigorous monitoring of the water quality before human consumption is recommended for all four studied water sources.

Human activities and natural factors determine the hydrogeochemical characteristics of karst groundwaters and their use as drinking water. This study assesses the hydrogeochemical characteristics of 14 karst water sources in the Apuseni Mountains (NW Romania) and their potential use as drinking water sources. As shown by the Durov and by the Piper diagrams, the chemical composition of the waters is typical of karst waters as it is dominated by HCO3− and Ca2+, having a circumneutral to alkaline pH and total dissolved solids ranging between 131 and 1092 mg L−1. The relation between the major ions revealed that dissolution is the main process contributing to the water chemistry. Limestone and dolostone are the main Ca and Mg sources, while halite is the main Na and Cl source. The Gibbs diagram confirmed the rock dominance of the water chemistry. The groundwater quality index (GWQI) showed that the waters are of excellent quality, except for two waters that displayed medium and good quality status. The quality of the studied karst waters is influenced by the geological characteristics, mainly by the water–rock interaction and, to a more limited extent, by anthropogenic activities. The investigated karst waters could be exploited as drinking water resources in the study area. The results of the present study highlight the importance of karst waters in the context of good-quality water shortage but also the vulnerability of this resource to anthropogenic influences.

Food consumption behavior during the COVID-19 pandemic has changed worldwide as a consequence of the restrictions imposed by law and/or due to the fear of contamination. Although some similarities are found among countries, there are still many particularities for each nation. The present study focused on Romanian consumers and their consumption behavior related to four main food categories: fruits and vegetables, meat and meat products, bread and bakery products, and milk and milk products. Frequency of buying, shopping habits, place of purchase, and concerns related to the place of purchasing food products during the COVID-19 pandemic were analyzed in comparison with the pre-COVID-19 period using descriptive statistics and inferential statistics regarding an online survey. Three types of behavior were identified as being related to the frequency of buying and to organizing a shopping list (less often, no change, more often). Two groups of consumers were identified as being related to the place of purchasing food: people with the same habits and people with new habits. Concerns related to the location of the stores and to the choice of buying directly from producers were also investigated using the ordered logistic regression. The empirical study revealed the new consumption patterns with a reflection on future trends.

Food waste represents an important aspect with social, economic, and environmental implications. As previous studies underlined, the COVID-19 pandemic led to changes in the food consumption patterns among consumers. The aim of the study was to investigate the main changes in household food waste management during the COVID-19 pandemic in Romania compared with the period before the COVID-19 pandemic. Factors affecting food waste were also analyzed. Data were collected among Romanian households using an online administrated questionnaire. The 784 usable questionnaires were analyzed using descriptive statistics and Cluster analysis. Consumers’ food shopping habits have become more sustainable during the pandemic, with a positive impact on waste management. The amount of the food losses decreased, people found ways to valorize the food scraps. The Cluster analysis of 25 food waste behavior factors lead to a 3 clusters solution: “wasters” (n = 264), “careless consumers” (n = 227), “careful consumers” (n = 359). While the “wasters” group was represented by consumers who chose to plan the shopping and the menu for the next period, were represented mainly by males with a lower level of education, the “careless consumers” did not choose to plan before going shopping, they discharge lower quantities of food compared with the first group. The “careful consumers” proved to be the most organized one, being preoccupied about the menu planning and reuse of leftovers. People became more conscious about their shopping habits; however, not all groups greatly improved their habits. The results indicate that more actions are needed to increase the awareness at the household level regarding food waste management and sustainable consumption during changing times.

In this paper, the production of a second-generation bioethanol from lignocellulosic vineyard cutting wastes was investigated in order to define the optimal operating conditions of the autohydrolysis pretreatment, chlorite delignification and simultaneous saccharification and fermentation (SSF). The autohydrolysis of vine-shoot wastes resulted in liquors containing mainly a mixture of monosaccharides, degradation products and spent solids (rich in cellulose and lignin), with potential utility in obtaining valuable chemicals and bioethanol. The autohydrolysis of the vine-shoot wastes was carried out at 165 and 180 °C for 10 min residence time, and the resulted solid and liquid phases composition were analysed. The resulted liquid fraction contained hemicellulosic sugars as a mixture of alpha (α) and beta (β) sugar anomers, and secondary by-products. The solid fraction was delignified using the sodium chlorite method for the separation of lignin and easier access of enzymes to the cellulosic sugars, and then, converted to ethanol by the SSF process. The maximum bioethanol production (6%) was obtained by autohydrolysis (165 °C), chlorite delignification and SSF process at 37 °C, 10% solid loading, 72 h. The principal component analysis was used to identify the main parameters that influence the chemical compositions of vine-shoot waste for different varieties.

The current study was conducted to assess the level and spatial distribution of metal pollution in surface water, soil, and sediment samples from the Arieș River basin, located in central Romania, an area impacted by various mining and industrial operations. Several pollution indices, spatial distributions, cluster analyses, principal component analyses, and heat maps were applied for evaluating the contamination level with Ni, Cu, Zn, Cd, Pb, Mn, As, and Hg in the area. Based on the results of the Heavy-Metal Pollution Index and of the Heavy-Metal Evaluation Index of the surface-water samples, the middle part of the Arieș River basin, near and downstream of the gold mine impoundment, was characterized by high pollution levels. The metal concentration was higher near the tailing impoundment, with increased levels of Cu, Ni, Zn, and Pb in the soil samples and As, Cd, Pb, Na, K, Ca, Mn, and Al in the sediment samples. Ca (23.7–219 mg/L), Mg (2.55–18.30 mg/L), K (0.64–14.70 mg/L), Al (0.06–22.80 mg/L), and Mn (0.03–22.40 mg/L) had the most remarkable spatial variation among the surface-water samples, while various metal contents fluctuated strongly among the sampling locations. Al varied from 743 to 19,8 mg/kg, Fe from 529 to 11,4 mg/kg, Ca from 2316 to 11,8 mg/kg, and Mg from 967 to 2547 mg/kg in the soil samples, and Al varied from 3106 to 8022 mg/kg, Fe from 314 to 5982 mg/kg, Ca from 1367 to 8308 mg/kg, and Mg from 412 to 1913 mg/kg in the sediment samples. The Potential Ecological Risk Index values for soil and sediments were in the orders Cu > Ni > Pb > Hg > Cr > As > Mn > Zn > Cd and As > Cu > Cr > Cd > Pb > Ni > Hg > Mn > Zn, respectively, and the highest values were found around the gold mine impoundment.

The objective of this study was to determine the chemical composition of eight vine shoot waste (VSW) varieties (Sauvignon Blanc, Pinot Noir, Feteasca Regala, Busuioaca de Bohotin, Muscat Ottonel, Cabernet Sauvignon, Feteasca Neagra and Feteasca Alba) regarding cellulose, hemicellulose, lignin, ash, moisture, mineral, protein, elemental analysis for the production of bioethanol. The highest cellulose and hemicellulose content (almost 65%) suggests that the VSW varieties can be used as raw material for bioethanol production. The most abundant minerals found in the VSW samples were Sr, Fe and Mn, which are indicators for vineyard production in Romania. The autohydrolysis fractionation method was applied for the separation of cellulosic and hemicellulosic sugars from the VSW varieties.

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