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The pervasiveness of microplastics in aquatic ecosystems has become a major environmental issue in recent years. The gradual dumping of plastic wastes, inadequate standard detection methods with specific removal techniques, and slow disposal rate of microplastics make it ubiquitous in the environment. Evidence shows that microplastics act as a potential vector by adsorbing different heavy metals, pathogens, and other chemical additives widely used in different raw plastic production. Microplastics are ingested by aquatic creatures such as fish and different crustaceans, and finally, people ingest them at the tertiary level of the food chain. This phenomenon is responsible for blocking the digestion tracts, disturbing the digestive behavior, finally decreasing the reproductive growth of entire living organisms. Because of these consequences, microplastics have become an increasing concern as a newly emerging potential threat, and therefore, the control of microplastics in aquatic media is required. This paper provides a critical analysis of existing and newly developed methods for detecting and separating microplastics from discharged wastewater, which are the ultimate challenges in the microplastic treatment systems. A critical study on the effect of microplastics on aquatic organisms and human health is also discussed. Thus, this analysis provides a complete understanding of entire strategies for detecting and removing microplastics and their associated issues to ensure a waste discharge standard to minimize the ultimate potential impact in aquatic environments.

Graphene oxide (GO) is a carbon‐based material, which is one atom thick sheet of graphite. The nanofillers have exceptional stiffness and strength owing to the presence of two‐dimensional graphene backbone. Especially owing to this reason, nanocomposites have been developed using GO for several applications. This review article explores the synthesis of GO from flake graphite. Main emphasis has been afforded on the preparation and characterization of GO nanocomposites, utilizing various industrial polymers for wide application in aerospace, biomedical, military, supercapacitors, electrical, sensor, and so on. Morphological characterization exploring the interaction and extent of dispersion of GO nanosheets in the polymer matrices is extensively accounted. From the reports, it is clear that exfoliation and strong interaction of GO tremendously improved the physical, mechanical, thermal, electrochemical, biocompatibility, and tribological properties of the added polymer. POLYM. COMPOS., 35:2297–2310, 2014. © 2014 Society of Plastics Engineers

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The present work deals with the functionalization of graphene sheet and preparation of functionalized graphene/linier low density polyethylene (LLDPE) nanocomposites by solution-mix techniques. Dodecyl amine (DA) has been used for the surface modification of graphene oxide (GO) and hydrazine as reducing agent. Fourier transform infrared (FTIR) spectra exhibits the appearance of new peaks in the functionalized graphene (DA-G), which suggests the functionalization of graphene by DA. X-ray diffraction (XRD) analysis infers the formation of fully exfoliated DA-G/LLDPE nanocomposites. The tensile strength (TS) and elongation at break (EB) of the composites are higher in comparison to neat LLDPE. The nanocomposites with only 0.5 wt.% of DA-G content results in TS and EB to be 17% and 10% higher compared to neat LLDPE. TGA shows that the thermal stability of the DA-G/LLDPE nanocomposites is higher compared to pure matrix polymer.