The role of the timing and order of quantum measurements is not just a fundamental question of quantum mechanics, but also a puzzling one. Any part of a quantum system that has finished evolving can be measured immediately or saved for later, without affecting the final results, regardless of the continued evolution of the rest of the system. In addition, the nonlocality of quantum mechanics, as manifested by entanglement, does not apply only to particles with spacelike separation, but also to particles with timelike separation. In order to demonstrate these principles, we generated and fully characterized an entangled pair of photons that have never coexisted. Using entanglement swapping between two temporally separated photon pairs, we entangle one photon from the first pair with another photon from the second pair. The first photon was detected even before the other was created. The observed two-photon state demonstrates that entanglement can be shared between timelike separated quantum systems.

Many important chemical and biochemical processes in the condensed phase are notoriously difficult to simulate numerically. Often this difficulty arises from the complexity of simulating dynamics resulting from coupling to structured, mesoscopic baths, for which no separation of time scales exists and statistical treatments fail. A prime example of such a process is vibrationally assisted charge or energy transfer. A quantum simulator, capable of implementing a realistic model of the system of interest, could provide insight into these processes in regimes where numerical treatments fail. We take a first step towards modeling such transfer processes using an ion trap quantum simulator. By implementing a minimal model, we observe vibrationally assisted energy transport between the electronic states of a donor and an acceptor ion augmented by coupling the donor ion to its vibration. We tune our simulator into several parameter regimes and, in particular, investigate the transfer dynamics in the nonperturbative regime often found in biochemical situations.

The high degree of control available over individual atoms enables precision tests of fundamental physical concepts. In this Letter, we experimentally study how precision measurements can be improved by preparing entangled states immune to the dominant source of decoherence. Using 40 Ca + ions, we explicitly demonstrate the advantage from entanglement on a precision test of local Lorentz invariance for the electron. Reaching the quantum projection noise limit set by quantum mechanics, we observe for bipartite entangled states the expected gain of a factor of two in the precision. Under specific conditions, multipartite entangled states may yield substantial further improvements. Our measurements improve the previous best limit for local Lorentz invariance of the electron using 40 Ca + ions by factor of two to four to about 5 × 10 −19 .

Current photon entangling schemes require resources that grow with the photon number. We present a new approach that generates quantum entanglement between many photons, using only a single source of entangled photon pairs. The different spatial modes, one for each photon as required by other schemes, are replaced by different time slots of only two spatial modes. States of any number of photons are generated with the same setup, solving the scalability problem caused by the previous need for extra resources. Consequently, entangled photon states of larger numbers than before are practically realizable.

Introducing structure into photon pair generation via spontaneous parametric down‐conversion (SPDC) is shown to be useful for controlling the output state and exploiting new degrees of freedom for quantum technologies. This paper presents a new method for simulating first‐ and second‐order correlations of the down‐converted photons in the presence of structured pump beams and shaped nonlinear photonic crystals. This method is nonperturbative, and thus accounts for high‐order effects, and can be made very efficient using parallel computing. Experimental results of photodetection and coincidence rates in complex spatial configurations are recovered quantitatively by this method. These include SPDC in 2D nonlinear photonic crystals, as well as with structured light beams such as Laguerre Gaussian and Hermite Gaussian beams. This simulation method reveals conservation rules for the down‐converted signal and idler beams that depend on the nonlinear crystal modulation pattern and the pump shape. This scheme can facilitate the design of nonlinear crystals and pumping conditions for generating non‐classical light with pre‐defined properties.