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The ambitious targets set by the International Maritime Organization for reducing greenhouse gas emissions from shipping require radical actions by all relevant stakeholders. In this context, the interest in high efficiency and low emissions (even zero in the case of hydrogen) fuel cell technology for maritime applications has been rising during the last decade, pushing the research developed by academia and industries. This paper aims to present a comparative review of the fuel cell systems suitable for the maritime field, focusing on PEMFC and SOFC technologies. This choice is due to the spread of these fuel cell types concerning the other ones in the maritime field. The following issues are analyzed in detail: (i) the main characteristics of fuel cell systems; (ii) the available technology suppliers; (iii) international policies for fuel cells onboard ships; (iv) past and ongoing projects at the international level that aim to assess fuel cell applications in the maritime industry; (v) the possibility to apply fuel cell systems on different ship types. This review aims to be a reference and a guide to state both the limitations and the developing potential of fuel cell systems for different maritime applications.

Climate change is driving the introduction of strict emission limits in the shipping sector favoring the introduction of alternative fuels, among which hydrogen. While the storage energy density of this energy vector is a key challenge that makes way to a variety of different solutions, from fossil fuel reformers to sodium borohydride systems, fuel cell systems are generally considered among the future ideal energy converters. Nevertheless very few fuel cell marine applications are available worldwide, none of them is related to a ship application, mainly because of the high power requirements. Fuel cells are relatively new in the shipping sector, up to now no civil industrial system has been commercialized yet while military applications rely only on the U212 submarine of the Italian and German Navy. The lack of favorable niche markets coupled with the strong conservative and traditional design principles held back the investment for optimized marine systems. For this reason, present and past projects made use of conveniently adapted automotive technologies into pilot demos, with particular focus on Proton Exchange Membrane Fuel Cell (PEMFC). However, ships requirements are largely different from automotive ones, not only for the power size that are in the range of MWs instead of kWs. On the other side, in order to take advantage of large scale production as well as of the modularity of fuel cell technology, the integrations of automotive or stationary based fuel cell subsystems, already available on the market, inside a dedicate modular marine system seems to be the solution pursued by many shipbuilders and contemplated by regulatory authorities. In hybrid system configurations, fuel cells are considered in combinations with batteries, another important technology under development, in order to take advantage of the superior energy performances of fuel cell systems and the highly power discharge dynamics of batteries. The need of fuel cell power systems for ships is pushing towards the creation of knowledge that requires laboratories able to challenge the abovementioned issues in order to give answers to shipbuilders and at a lower level also to rule makers.

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PEM Fuel Cells are considered among the most promising technologies for hydrogen utilization in both stationary and automotive applications. The number of FC installations on board ships – alone or in hybrid configuration with batteries – is increasing significantly, although international regulations that drive their installation are still missing. In this scenario, the project TecBia aims to identify a dedicated test protocol and the best commercial PEMFC technology for marine applications, assessing the integration of a 140 kW PEMFC system on the Zero Emission Ultimate Ship (ZEUS) vessel. The system design and technology provider has been chosen after a technical comparison based on a dedicated experimental campaign. The experimental campaign had two goals: (i) analyse the performance of the different PEMFC systems to define the best characteristics for maritime applications; (ii) verify the compliance with naval requirements with reference to current and future standards. The present study shows the resulting test protocol for FC Systems (FCS) for maritime applications, defined starting from the existing international regulations on FCS installations and on naval environment requirements; the results of its application on the commercial system chosen for the installation on ZEUS are reported.

Hydrogen is a promising energy carrier to allow the reach of the zero-emission targets established for the next years. Polymeric Electrolyte Membrane FC are studied inside the HI-SEA laboratory of the University of Genoa, to assess the opportunities of this technology on marine applications. Here, 8 PEMFC stacks, sized 30 kW each for a total power installation of 240 kW, have been tested to draw guidelines for the best system design onboard ships and to deepen the know-how on the experimental management of the technology. During the tests, it was possible to observe the reciprocal influence of some parameters, which may influence the system efficiency. In this work, a statistical investigation is developed to quantify the cell voltage variation correlated to the values of temperature and current. This has been possible thanks to Design Expert (DE), a software developed by Stat-EASE, Inc. Through the Design of Experiment approach, it is possible to evaluate the significance of variables in the FC system, called factors. The experiment under consideration is also characterized by non-controllable factors, cause of disturbances that induce further variability in the response. Eventually, it was possible to analyse the significance of the parameters involved, to build a regression model by performing the analysis of variance with which the significant values are identified, and to assess the presence of outliers.

The ZEUS (Zero Emission Ultimate Ship), developed in the framework of the national research project TecBia conducted by Fincantieri and co-founded by Italian Ministry of Economic Development, is a 25m length vessel characterized by a zero-emissions propulsion system. The on-board power generation is provided by 4 PEM Fuel Cell modules (140 kW power installation) fed by hydrogen stored into 48 Metal Hydride tanks (MH). PEMFC and MH thermal systems are coupled to recover the heat produced by PEMFC and to feed the endothermic dissociation reactions of hydrogen from MHs. This paper provides a Matlab-Simulink model to simulate the dynamic behaviour of the PEMFC power generation system and the thermal coupling with MH racks installed onboard. Three typical operative profiles are simulated to verify the thermal management control system and the impact of transient conditions on the propulsion plant. Furthermore, the effects of the major exogenous parameters are investigated. Results verify that thermal coupling between the two systems is guaranteed; however, an excessive load increase can lead the stacks to operate under non-optimal conditions for significant periods of time. The effect of exogenous parameters has been verified to be negligible and does not significantly affect the control system.

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