As an exoplanet transits its host star, some of the light from the star is absorbed by the atoms and molecules in the planets atmosphere, causing the planet to seem bigger; plotting the planets observed size as a function of the wavelength of the light produces a transmission spectrum 1 . Measuring the tiny variations in the transmission spectrum, together with atmospheric modelling, then gives clues to the properties of the exoplanets atmosphere. Chemical species composed of light elementssuch as hydrogen, oxygen, carbon, sodium and potassiumhave in this way been detected in the atmospheres of several hot giant exoplanets [2][3][4][5] , but molecules composed of heavier elements have thus far proved elusive. Nonetheless, it has been predicted that metal oxides such as titanium oxide (TiO) and vanadium oxide occur in the observable regions of the very hottest exoplanetary atmospheres, causing thermal inversions on the dayside 6, 7 . Here we report the detection of TiO in the atmosphere of the hot-Jupiter planet WASP-19b. Our combined spectrum, with its wide spectral coverage, reveals the presence of TiO (to a confidence level of 7.7σ), a strongly scattering haze (7.4σ) and sodium (3.4σ), and confirms the presence of water (7.9σ) in the atmosphere 5,8 .Hot Jupiters are gas-giant exoplanets with sizes like that of Jupiter but much shorter orbital periods. WASP-19b is the shortest-period hot Jupiter to be discovered so far 9 , and has an excessively bloated radius, owing to the extreme radiation that it receives from its host star; as a result of this radiation, the planets effective temperature is more than 2,000 K (obtained via secondaryeclipse measurements 10 ). It is thought that high atmospheric temperatures imply the presence of metal oxides such as TiO, but despite extensive searches 11, 12 a definitive detection of metal oxides in exoplanetary atmospheres has proved elusive.We observed three transits of European Southern Observatorys Very Large Telescope (VLT), using the low-resolution FORS2 spectrograph. By using three of FORS2s grisms600B (blue), 600RI (green) and 600z (red), thereby covering the entire visible-wavelength domain (0.431.04 µm)together with the multi-object spectroscopy configuration, we were able to obtain relatively high-resolution, precise, broadband transmission spectra. Such results were made possible through optimized observing strategies 13 and careful design of the observing mask used for the multi-object observations: this has slits about 30 wide, which minimized differential losses owing to variations in telescope guiding and seeing conditions. The observations presented here were made between 11 November 2014 and 29 February 2016.For each set of observations, we obtained a series of spectra for the main target (WASP-19), as well as for several comparison stars. After standard data-reduction steps, we integrated those spectra for the largest common wavelength domain and 10-nm bins, to produce the 'white' and 'spectrophotometric' light curves, respectively. To correct for the imp...

We present FORS2 (attached to ESO's Very Large Telescope) observations of the exoplanet WASP-17b during its primary transit, for the purpose of differential spectrophotometry analysis. We use the instrument in its Mask eXchange Unit (MXU) mode to simultaneously obtain low resolution spectra of the planet hosting star, as well as several reference stars in the field of view. The integration of these spectra within broadband and smaller 100Å bins provides us with 'white' and spectrophotometric light curves, from 5700 to 8000Å. Through modelling the white light curve, we obtain refined bulk and transit parameters of the planet, as well as wavelength-dependent variations of the planetary radius from smaller spectral bins through which the transmission spectrum is obtained. The inference of transit parameters, as well as the noise statistics, is performed using a Gaussian Process model. We achieve a typical precision in the transit depth of a few hundred parts per million from various transit light curves. From the transmission spectra we rule out a flat spectrum at >3σ and detect marginal presence of the pressure-broadened sodium wings. Furthermore, we detect the wing of the potassium absorption line in the upper atmosphere of the planet with 3-σ confidence, both facts pointing to a relatively shallow temperature gradient of the atmosphere. These conclusions are mostly consistent with previous studies of this exo-atmosphere, although previous potassium measurements have been inconclusive.

In the past few years, the study of exoplanets has evolved from being pure discovery, then being more exploratory in nature and finally becoming very quantitative. In particular, transmission spectroscopy now allows the study of exoplanetary atmospheres. Such studies rely heavily on space-based or large ground-based facilities, because one needs to perform time-resolved, high signal-to-noise spectroscopy. The very recent exchange of the prisms of the FORS2 atmospheric diffraction corrector on ESO's Very Large Telescope should allow us to reach higher data quality than was ever possible before. With FORS2, we have obtained the first optical groundbased transmission spectrum of WASP-19b, with 20 nm resolution in the 550-830 nm range. For this planet, the data set represents the highest resolution transmission spectrum obtained to date. We detect large deviations from planetary atmospheric models in the transmission spectrum redwards of 790 nm, indicating either additional sources of opacity not included in the current atmospheric models for WASP-19b or additional, unexplored sources of systematics. Nonetheless, this work shows the new potential of FORS2 for studying the atmospheres of exoplanets in greater detail than has been possible so far.

Ultra-hot Jupiters (UHJs) are gas giants with very high equilibrium temperatures. In recent years, multiple chemical species, including various atoms and ions, have been discovered in their atmospheres. Most of these observations have been performed with transmission spectroscopy, although UHJs are also ideal targets for emission spectroscopy due to their strong thermal radiation. We present high-resolution thermal emission spectroscopy of the transiting UHJ KELT-20b/MASCARA-2b. The observation was performed with the CARMENES spectrograph at orbital phases before and after the secondary eclipse. We detected atomic Fe using the cross-correlation technique. The detected Fe lines are in emission, which unambiguously indicates a temperature inversion on the dayside hemisphere. We furthermore retrieved the temperature structure with the detected Fe lines. The result shows that the atmosphere has a strong temperature inversion with a temperature of 4900 ± 700 K and a pressure of 10−4.8−1.1+1.0 bar at the upper layer of the inversion. A joint retrieval of the CARMENES data and the TESS secondary eclipse data returns a temperature of 2550−250+150 K and a pressure of 10−1.5−0.6+0.7 bar at the lower layer of the temperature inversion. The detection of such a strong temperature inversion is consistent with theoretical simulations that predict an inversion layer on the dayside of UHJs. The joint retrieval of the CARMENES and TESS data demonstrates the power of combing high-resolution emission spectroscopy with secondary eclipse photometry in characterizing atmospheric temperature structures.

We derive the 0.01 µm binned transmission spectrum, between 0.74 and 1.0 µm, of WASP-80b from low resolution spectra obtained with the FORS2 instrument attached to ESO's Very Large Telescope. The combination of the fact that WASP-80 is an active star, together with instrumental and telluric factors, introduces correlated noise in the observed transit light curves, which we treat quantitatively using Gaussian Processes. Comparison of our results together with those from previous studies, to theoretically calculated models reveals an equilibrium temperature in agreement with the previously measured value of 825K, and a sub-solar metallicity, as well as an atmosphere depleted of molecular species with absorption bands in the IR ( 5σ). Our transmission spectrum alone shows evidence for additional absorption from the potassium core and wing, whereby its presence is detected from analysis of narrow 0.003 µm bin light curves ( 5σ). Further observations with visible and near-UV filters will be required to expand this spectrum and provide more in-depth knowledge of the atmosphere. These detections are only made possible through an instrument-dependent baseline model and a careful analysis of systematics in the data.

The He I λ10833 Å triplet is a powerful tool for characterising the upper atmosphere of exoplanets and tracing possible mass loss. Here, we analysed one transit of GJ 1214 b observed with the CARMENES high-resolution spectrograph to study its atmosphere via transmission spectroscopy around the He I triplet. Although previous studies using lower resolution instruments have reported non-detections of He I in the atmosphere of GJ 1214 b, we report here the first potential detection. We reconcile the conflicting results arguing that previous transit observations did not present good opportunities for the detection of He I, due to telluric H2O absorption and OH emission contamination. We simulated those earlier observations, and show evidence that the planetary signal was contaminated. From our single non-telluric-contaminated transit, we determined an excess absorption of 2.10−0.50+0.45% (4.6 σ) with a full width at half maximum (FWHM) of 1.30−0.25+0.30 Å. The detection of He I is statistically significant at the 4.6 σ level, but repeatability of the detection could not be confirmed due to the availability of only one transit. By applying a hydrodynamical model and assuming an H/He composition of 98/2, we found that GJ 1214 b would undergo hydrodynamic escape in the photon-limited regime, losing its primary atmosphere with a mass-loss rate of (1.5–18) × 1010 g s−1 and an outflow temperature in the range of 2900–4400 K. Further high-resolution follow-up observations of GJ 1214 b are needed to confirm and fully characterise the detection of an extended atmosphere surrounding GJ 1214 b. If confirmed, this would be strong evidence that this planet has a primordial atmosphere accreted from the original planetary nebula. Despite previous intensive observations from space- and ground-based observatories, our He I excess absorption is the first tentative detection of a chemical species in the atmosphere of this benchmark sub-Neptune planet.

Atmospheres of highly irradiated gas giant planets host a large variety of atomic and ionic species. Here we observe the thermal emission spectra of the two ultra-hot Jupiters WASP-33b and KELT-20b/MASCARA-2b in the near-infrared wavelength range with CARMENES. Via high-resolution Doppler spectroscopy, we searched for neutral silicon (Si) in their dayside atmospheres. We detect the Si spectral signature of both planets via cross-correlation with model spectra. Detection levels of 4.8σ and 5.4σ, respectively, are observed when assuming a solar atmospheric composition. This is the first detection of Si in exoplanet atmospheres. The presence of Si is an important finding due to its fundamental role in cloud formation and, hence, for the planetary energy balance. Since the spectral lines are detected in emission, our results also confirm the presence of an inverted temperature profile in the dayside atmospheres of both planets.

The formation of hazes at microbar pressures has been explored by theoretical models of exoplanet atmospheres to explain Rayleigh scattering and/or featureless transmission spectra; however observational evidence of aerosols in the low-pressure formation environments has proved elusive. Here, we show direct evidence of aerosols existing at ∼1 microbar pressures in the atmosphere of the warm sub-Saturn WASP-69b using observations taken with the Space Telescope Imaging Spectrograph and Wide Field Camera 3 instruments on the Hubble Space Telescope. The transmission spectrum shows a wavelength-dependent slope induced by aerosol scattering that covers 11 scale heights of spectral modulation. Drawing on the extensive studies of haze in our solar system, we model the transmission spectrum based on a scaled version of Jupiter’s haze-density profile to show that the WASP-69b transmission spectrum can be produced by scattering from an approximately constant density of particles extending throughout the atmospheric column from 40 millibar to microbar pressures. These results are consistent with theoretical expectations based on microphysics of the aerosol particles that have suggested haze can exist at microbar pressures in exoplanet atmospheres.