Optically active mixed alkoxy orthotitanates with general formula Ti(ORI)2(OR2)(OR 3) (R I = Et, Bun; R 2 = CH2CH2OCOC(MeI=CH2; R 3 = menthyl, CH(Me)CH2Me, CH(Ph)CH(NHMe)Me. CH(C9H6N)(CgHL4N)) were obtained for the first time by tmnsesterification. The Ti TM monomers synthesized were characterized by elemental analysis. ozonolysis, and IH and I;C NMR and IR spectroscopy. Polymer products with optical activity were obtained by liquid phase radical copolymerization of TilV-containing monomers.
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