Catalytic properties of rhenium. Communication 1. Rhenium as a dehydrogenation catalyst

Balandin, Alexander A.; Karpeiskaya, E. I.; Tolstopyatova, A. A.

doi:10.1007/bf00918568

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“…The catalytic activity of rhenium was proved in the past. The activity of rhenium deposited on charcoal to catalyze cyclohexane and cumene dehydrogenation was examined in the late 1950s [9]. The catalyst was produced by sorption of ammonium perrhenate within charcoal in the presence of nitric acid with subsequent reduction with hydrazine hydrate and hydrogen gas.…”

Section: Introductionmentioning

confidence: 99%

Active Carbon Modified by Rhenium Species as a Perspective Supercapacitor Electrode

et al. 2020

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We have reported the synthesis of a new kind of composite combining a rhenium precursor and active carbon. Similarly to other refractory metals, rhenium exhibits several oxidation states that makes it an ideal candidate for redox-type energy storage materials. A simple impregnation of pretreated active carbon with ammonium perrhenate allowed to produce an electrode material with an enhanced specific capacitance. There was not any observed detrimental effect of metal species on the cycle life of the electrode. A small increase in charge transfer resistance was counter-balanced by the improved impedance in the whole examined range.

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Section: Introductionmentioning

confidence: 99%