Cl as Solvents. -Trialkylalanes (II) react with cyclic acetals in chlorine-containing solvents under mild conditions to furnish products of reductive cleavage [cf. (III), (VI)] and reductive alkylation [cf. (IV), (VII)]. Orthoformates (VIII) furnish dialkylacetals (IX) under analogous conditions. -(GAFAROVA*, Y. T.; DEKHTYAR', E. F.; DEKHTYAR', T. F.; FATYKHOV, A. A.; SPIRIKHIN, L. V.; VOSTRIKOVA, O. S.; ZLOTSKII, S. S.; DOKICHEV, V. A.; Russ.
2002 aldehyde derivatives aldehyde derivatives (acyclic compounds) P 0190 43 -088 Regioselective Splitting of 3-Alkyl-1-ethylaluminacyclopentanes (I) with Orthoformates (II) as a New Route to 1-Functionalized 4-Methylalkanes (III). --(VOSTRIKOVA, O. S.; DEKHTYAR, E. F.; ZLOTSKII, S. S.; DOKICHEV, V. A.; Russ.
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