No abstract

It has been known since the 1960s that the layers of Na and K atoms, which occur between 80 and 105 km in the Earth's atmosphere as a result of meteoric ablation, exhibit completely different seasonal behavior. In the extratropics Na varies annually, with a pronounced wintertime maximum and summertime minimum. However, K varies semiannually with a small summertime maximum and minima at the equinoxes. This contrasting behavior has never been satisfactorily explained. Here we use a combination of electronic structure and chemical kinetic rate theory to determine two key differences in the chemistries of K and Na. First, the neutralization of K + ions is only favored at low temperatures during summer. Second, cycling between K and its major neutral reservoir KHCO 3 is essentially temperature independent. A whole atmosphere model incorporating this new chemistry, together with a meteor input function, now correctly predicts the seasonal behavior of the K layer.

The National Aeronautics and Space Administration (NASA) Thermosphere Ionosphere Mesosphere Energetics and Dynamics (TIMED) Sounding of the Atmosphere using Broadband Radiometry (SABER) instrument performs near‐global measurements of the vertical kinetic temperature (Tk) profiles and volume mixing ratios of various trace species (including O3, CO2, and H2O), with data available from 2002 to present. In this work, the first comparative study of the latest publically available SABER version 2.0 operational retrieval is reported in order to assess the performance of satellite Tk profiles relative to high‐resolution ground‐based lidar profiles. Collocated multiyear seasonal average Tk profiles were compared at nine different locations, representing a variety of different latitudes. In general, the SABER v2.0 and lidar mean seasonal Tk profiles agree well, with the smallest absolute values of ΔTk (z) (SABER minus lidar) found between 85 and 95 km, where the respective SABER and lidar uncertainties were smallest. At altitudes ≥100 km, the SABER Tk (z) typically exhibited warmer temperatures relative to the lidar Tk (z) profiles, whereas for altitudes ≤85 km, SABER Tk (z) was cooler. Relative to lidar, SABER tends to exhibit a warm bias during high‐latitude summertime, with the reasons for this currently still unclear. Overall, SABER was able to reproduce the general latitude‐ and season‐specific variations in the lidar Tk profiles and shown to be statistically similar for most seasons, at most locations, for the majority of altitudes, and with no overall bias.

Precipitation is an important component of the climate system, and the accurate representation of the diurnal rainfall cycle is a key test of model performance. Although the modeling of precipitation in the cooler midlatitudes has improved, in the tropics substantial errors still occur. Precipitation from the operational ECMWF forecast model is compared with satellite-derived products from the Tropical Rainfall Measuring Mission (TRMM) Multisatellite Precipitation Analysis (TMPA) and TRMM Precipitation Radar (PR) to assess the mean annual and seasonal diurnal rainfall cycles. The analysis encompasses the global tropics and subtropics (40°N–40°S) over a 7-yr period from 2004 to 2011. The primary aim of the paper is to evaluate the ability of an operational numerical model and satellite products to retrieve subdaily rainfall. It was found that during the first half of the analysis period the ECMWF model overestimated precipitation by up to 15% in the tropics, although after the implementation of a new convective parameterization in November 2007 this bias fell to about 4%. The ECMWF model poorly represented the diurnal cycle, simulating rainfall too early compared to the TMPA and TRMM PR products; the model simulation of precipitation was particularly poor over Indonesia. In addition, the model did not appear to simulate mountain-slope breezes well or adequately capture many of the characteristics of mesoscale convective systems. The work highlights areas for further study to improve the representation of subgrid-scale processes in parameterization schemes and improvements in model resolution. In particular, the proper representation of subdaily precipitation in models is critical for hydrological modeling and flow forecasting.

The meteoric metal layers act as unique tracers of chemistry and dynamics in the upper atmosphere. Existing lidar studies from a few locations show that K exhibits a semiannual seasonality (winter and summer maxima), quite unlike the annual seasonality (winter maximum and summer minimum) seen with Na and Fe. This work uses spaceborne observations made with the Optical Spectrograph and InfraRed Imager System instrument on the Odin satellite to retrieve the near‐global K layer for the first time. The satellite data (2004 to mid‐2013) are used to validate the implementation of a recently proposed potassium chemistry scheme in a whole atmosphere chemistry climate model, which provides a chemical basis for this semiannual seasonal behavior. The satellite and model data show that this semiannual seasonality is near global in extent, with the strongest variation at middle and high latitudes. The column abundance, centroid layer height, and root‐mean‐square width of the K layer are consistent with the limited available lidar record. The K data set is then used to investigate the impact of polar mesospheric clouds on the metal layers at high latitudes during summer. Finally, the occurrence frequency of sporadic K layers and their possible link to sporadic E layers are examined.

Metal species, produced by meteoric ablation, act as useful tracers of upper atmosphere dynamics and chemistry. Of these meteoric metals, K is an enigma: at extratropical latitudes, limited available lidar data show that the K layer displays a semiannual seasonal variability, rather than the annual pattern seen in other metals such as Na and Fe. Here we present the first near-global K retrieval, where K atom number density profiles are derived from dayglow measurements made by the Optical Spectrograph and Infrared Imager System spectrometer on board the Odin satellite. This robust retrieval produces density profiles with typical layer peak errors of ±15% and a 2 km vertical grid resolution. We demonstrate that these retrieved profiles compare well with available lidar data and show for the first time that the unusual semiannual behavior is near-global in extent. This new data set has wider applications for improving understanding of the K chemistry and of related upper atmosphere processes.

The meteoric metal layers (Na, Fe, and K)—which form as a result of the ablation of incoming meteors—act as unique tracers for chemical and dynamical processes that occur within the upper mesosphere/lower thermosphere region. In this work, we examine whether these metal layers are sensitive indicators of decadal long‐term changes within the upper atmosphere. Output from a whole‐atmosphere climate model is used to assess the response of the Na, K, and Fe layers across a 50 year period (1955–2005). At short timescales, the K layer has previously been shown to exhibit a very different seasonal behavior compared to the other metals. Here we show that this unusual behavior is also exhibited at longer timescales (both the ~11 year solar cycle and 50 year periods), where K displays a much more pronounced response to atmospheric temperature changes than either Na or Fe. The contrasting solar cycle behavior of the K and Na layers predicted by the model is confirmed using satellite and lidar observations for the period 2004–2013.

Abstract. During the last decade, several limb sounding satellites have measured the global sodium (Na) number densities in the mesosphere and lower thermosphere (MLT). Datasets are now available from Global Ozone Monitoring by Occultation of Stars (GOMOS), the SCanning Imaging Absorption spectroMeter for Atmospheric CHartography (SCIAMACHY) (both on Envisat) and the Optical Spectrograph and InfraRed Imager System (OSIRIS) (on Odin). Furthermore, global model simulations of the Na layer in the MLT simulated by the Whole Atmosphere Community Climate Model, including the Na species (WACCM-Na), are available. In this paper, we compare these global datasets.The observed and simulated monthly averages of Na vertical column densities agree reasonably well with each other. They show a clear seasonal cycle with a summer minimum most pronounced at the poles. They also show signs of a semi-annual oscillation in the equatorial region. The vertical column densities vary from 0.5 × 10 9 to 7 × 10 9 cm −2 near the poles and from 3 × 10 9 to 4 × 10 9 cm −2 at the Equator. The phase of the seasonal cycle and semi-annual oscillation shows small differences between the Na amounts retrieved from different instruments. The full width at half maximum of the profiles is 10 to 16 km for most latitudes, but significantly smaller in the polar summer. The centroid altitudes of the measured sodium profiles range from 89 to 95 km, whereas the model shows on average 2 to 4 km lower centroid altitudes. This may be explained by the mesopause being 3 km lower in the WACCM simulations than in measurements. Despite this global 2-4 km shift, the model captures well the latitudinal and temporal variations. The variation of the WACCM dataset during the year at different latitudes is similar to the one of the measurements. Furthermore, the differences between the measured profiles with different instruments and therefore different local times (LTs) are also present in the model-simulated profiles. This capturing of latitudinal and temporal variations is also found for the vertical column densities and profile widths.