The authors investigated the field emission from vertically well-aligned zinc oxide (ZnO) nanoneedles grown on the Au∕Ti∕n-Si (100) substrate using metal organic chemical vapor deposition. The turn-on field of ZnO nanoneedles was about 0.85V∕μm at the current density of 0.1μA∕cm2, and the emission current density of 1mA∕cm2 was achieved at the applied electric field of 5.0V∕μm. The low turn-on field of the ZnO nanoneedles was attributed to very sharp tip morphology, and the high emission current density was mainly caused by the formation of the stable Ohmic contact between the ZnO nanoneedles and Au film.
Electromagnetic (EM) wave emissions from wearable or flexible smart display devices can cause product malfunction and have a detrimental effect on human health. Therefore, EM shielding strategies are becoming increasingly necessary. Consequently, herein, we prepared a transparent acrylic polymer-coated/reduced graphene oxide/silver nanowire (Ag NW) (A/RGO/SANW) EM interference (EMI) shielding film via liquid-to-vapor pressure-assisted wet sintering. The film exhibited enhanced Ag NW network formation and antireflection (AR) effects. The wet-sintered Ag NW shielding film had a threshold radius of curvature (ROC) of 0.31 mm at a film thickness of 100 μm, demonstrating its high flexibility, whereas the conventional indium tin oxide (ITO) shielding film had a threshold ROC of ∼5 mm. The EMI shielding effectiveness (SE) of the A/RGO/SANW multilayer film was approximately twice that of the ITO film at a similar relative transmittance (84-85%). The optical relative reflectance of the Ag NW layer was reduced due to the AR effect, and the visible-light transmittance was considerably improved owing to the different refractive indices in the multilayer shielding film. Because the acrylic coating layer had a high contact angle, the multilayer film exhibited high temperature and humidity durability with little change in the SE over 500 h at 85 °C and 85% relative humidity. The multilayer film comprising wet-sintered Ag NW exhibited high flexibility and humidity durability, high shielding performance (more than 24 dB at a relative transmittance of 85% or more), and high mass productivity, making it highly applicable for use as a transparent shielding material for future flexible devices.
Nanostructured semiconducting metal oxides and particularly nanofiber-based photoelectrodes can provide enhanced energy conversion efficiencies in dye-sensitized solar cells ͑DSSCs͒. In this study ZnO/poly͑vinyl acetate͒ composite nanofiber mats were directly electrospun onto a glass substrate coated with F : SnO 2 , then hot pressed at 120°C and calcined at 450°C. This resulted in multiple nanofiber networks composed of a twisted structure of 200-500 nm diameter cores with ϳ30 nm single grains. The DSSCs using ZnO nanofiber mats exhibited a conversion efficiency of 1.34% under 100 mW/ cm 2 ͑AM-1.5G͒ illumination.
Thermoelectric cooling module (TEM) which is electric device has a mechanical stress because of temperature gradient in itself. It means that structure of TEM is vulnerable in an aspect of reliability but research on reliability of TEM was not performed a lot. Recently, the more the utilization of thermoelectric cooling devices grows, the more the needs for life prediction and improvement are increasing. In this paper, we investigated life distribution, shape parameter of the TEM through accelerated life test (ALT). And we discussed about how to enhance life of TEM through the Physics-of-failure. Experimental results of ALT showed that the thermoelectric cooling module follows the Weibull distribution, shape parameter of which is 3.6. The acceleration model is coffin Coffin-Manson and material constant is 1.8.
A polycrystalline silicon thin-film transistor (TFT) technology, field-aided lateral crystallization (FALC), has been explored. Polycrystalline silicon thin film, as an active layer, was prepared by applying an electric field to amorphous silicon film during Ni metal-induced lateral crystallization (MILC). Compared with the conventional metal-induced lateral crystallization thin-film transistors (MILC TFTs), these field-aided lateral crystallization thin-film transistors (FALC TFTs) show a low off-state leakage current of 1.79×10−11 A at Vg=−10 V and a high on/off current ratio of 8.82×105. Moreover, the threshold voltage is lower and field-effect mobility is higher than those of MILC TFTs. Therefore, the possibility of high-performance and low-temperature (<500 °C) polycrystalline silicon TFTs was demonstrated by using FALC technology.
The photochemical tunability of the charge-transport mechanism in metal-oxide semiconductors is of great interest since it may offer a facile but effective semiconductor-to-metal transition, which results from photochemically modified electronic structures for various oxide-based device applications. This might provide a feasible hydrogen (H)-radical doping to realize the effectively H-doped metal oxides, which has not been achieved by thermal and ion-implantation technique in a reliable and controllable way. In this study, we report a photochemical conversion of InGaZnO (IGZO) semiconductor to a transparent conductor via hydrogen doping to the local nanocrystallites formed at the IGZO/glass interface at room temperature. In contrast to thermal or ionic hydrogen doping, ultraviolet exposure of the IGZO surface promotes a photochemical reaction with H radical incorporation to surface metal-OH layer formation and bulk H-doping which acts as a tunable and stable highly doped n-type doping channel and turns IGZO to a transparent conductor. This results in the total conversion of carrier conduction property to the level of metallic conduction with sheet resistance of ∼16 Ω/□, room temperature Hall mobility of 11.8 cm(2) V(-1) sec(-1), the carrier concentration at ∼10(20) cm(-3) without any loss of optical transparency. We demonstrated successful applications of photochemically highly n-doped metal oxide via optical dose control to transparent conductor with excellent chemical and optical doping stability.
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