Organic carbon (OC) and elemental carbon (EC) are operationally de ned by the analysis methods, and different methods give in different results. The IMPROVE (Interagency Monitoring of Protected Visual Environments) and NIOSH (National Institute of Occupational Safety and Health) thermal evolution protocols present different operational de nitions. These protocols are applied to 60 ambient and source samples from different environments using the same instrument to quantify differences in implemented protocols on the same instrument. The protocols are equivalent for total carbon sampled on quartz-ber lters. NIOSH EC was typically less than half of IMPROVE EC. The primary difference is the allocation of carbon evolving at the NIOSH 850 ± C temperature in a helium atmosphere to the OC rather than EC fraction. Increasing light transmission and re ectance during this temperature step indicate that this fraction should be classi ed as EC. When this portion of NIOSH OC is added to NIOSH EC, the IMPROVE and NIOSH analyses are in good agreement. The most probable explanation is that mineral oxides in the complex particle mixture on the lter are supplying oxygen to neighboring carbon particles at this high temperature. This has been demonstrated by the principle of the thermal manganese oxidation method that is also commonly used to distinguish OC from EC. For both methods, the optical pyrolysis adjustment to the EC fractions was always higher for transmittance than for re ectance. This is a secondary cause of differences between the two methods, with transmittance resulting in a lower EC loading than re ectance. The difference was most pronounced for very black lters on which neither re ectance nor transmittance accurately detected further blackening due to pyrolysis.
Organic carbon (OC) and elemental carbon (EC) are operationally de ned by the analysis methods, and different methods give in different results. The IMPROVE (Interagency Monitoring of Protected Visual Environments) and NIOSH (National Institute of Occupational Safety and Health) thermal evolution protocols present different operational de nitions. These protocols are applied to 60 ambient and source samples from different environments using the same instrument to quantify differences in implemented protocols on the same instrument. The protocols are equivalent for total carbon sampled on quartz-ber lters. NIOSH EC was typically less than half of IMPROVE EC. The primary difference is the allocation of carbon evolving at the NIOSH 850 ± C temperature in a helium atmosphere to the OC rather than EC fraction. Increasing light transmission and re ectance during this temperature step indicate that this fraction should be classi ed as EC. When this portion of NIOSH OC is added to NIOSH EC, the IMPROVE and NIOSH analyses are in good agreement. The most probable explanation is that mineral oxides in the complex particle mixture on the lter are supplying oxygen to neighboring carbon particles at this high temperature. This has been demonstrated by the principle of the thermal manganese oxidation method that is also commonly used to distinguish OC from EC. For both methods, the optical pyrolysis adjustment to the EC fractions was always higher for transmittance than for re ectance. This is a secondary cause of differences between the two methods, with transmittance resulting in a lower EC loading than re ectance. The difference was most pronounced for very black lters on which neither re ectance nor transmittance accurately detected further blackening due to pyrolysis.
The Interagency Monitoring of Protected Visual Environments (IMPROVE) particle monitoring network consists of approximately 160 sites at which fine particulate matter (PM2.5) mass and major species concentrations and course particulate matter (PM10) mass concentrations are determined by analysis of 24-hr duration sampling conducted on a 1-day-in-3 schedule A simple algorithm to estimate light extinction from the measured species concentrations was incorporated in the 1999 Regional Haze Rule as the basis for the haze metric used to track haze trends. A revised algorithm was developed that is more consistent with the recent atmospheric aerosol literature and reduces bias for high and low light extinction extremes. The revised algorithm differs from the original algorithm in having a term for estimating sea salt light scattering from Cl(-) ion data, using 1.8 instead of 1.4 for the mean ratio of organic mass to measured organic carbon, using site-specific Rayleigh scattering based on site elevation and mean temperature, employing a split component extinction efficiency associated with large and small size mode sulfate, nitrate and organic mass species, and adding a term for nitrogen dioxide (NO2) absorption for sites with NO2 concentration information. Light scattering estimates using the original and the revised algorithms are compared with nephelometer measurements at 21 IMPROVE monitoring sites. The revised algorithm reduces the underprediction of high haze periods and the overprediction of low haze periods compared with the performance of the original algorithm. This is most apparent at the hazier monitoring sites in the eastern United States. For each site, the PM10 composition for days selected as the best 20% and the worst 20% haze condition days are nearly identical regardless of whether the basis of selection was light scattering from the original or revised algorithms, or from nephelometer-measured light scattering.
[1] A field campaign designed to investigate the second indirect aerosol effect (reduction of precipitation by anthropogenic aerosols which produce more numerous and smaller cloud droplets) was conducted during winter in the northern Rocky Mountains of Colorado. Combining remote sensing and in-situ mountain-top measurements it was possible to show higher concentrations of anthropogenic aerosols ($1 mg m À3) altered the microphysics of the lower orographic feeder cloud to the extent that the snow particle rime growth process was inhibited, or completely shut off, resulting in lower snow water equivalent precipitation rates.
The 14‐month‐long (December 1999 to February 2001) Central California Regional PM10/PM2.5 Air Quality Study (CRPAQS) consisted of acquiring speciated PM2.5 measurements at 38 sites representing urban, rural, and boundary environments in the San Joaquin Valley air basin. The study's goal was to understand the development of widespread pollution episodes by examining the spatial variability of PM2.5, ammonium nitrate (NH4NO3), and carbonaceous material on annual, seasonal, and episodic timescales. It was found that PM2.5 and NH4NO3 concentrations decrease rapidly as altitude increases, confirming that topography influences the ventilation and transport of pollutants. High PM2.5 levels from November 2000 to January 2001 contributed to 50–75% of annual average concentrations. Contributions from organic matter differed substantially between urban and rural areas. Winter meteorology and intensive residential wood combustion are likely key factors for the winter‐nonwinter and urban‐rural contrasts that were observed. Short‐duration measurements during the intensive operating periods confirm the role of upper air currents on valley‐wide transport of NH4NO3. Zones of representation for PM2.5 varied from 5 to 10 km for the urban Fresno and Bakersfield sites, and increased to 15–20 km for the boundary and rural sites. Secondary NH4NO3 occurred region‐wide during winter, spreading over a much wider geographical zone than carbonaceous aerosol.
Environmental contextAerosol water-soluble organic carbon is a complex mixture of thousands of organic compounds which may have a significant influence on the climate-relevant properties of atmospheric aerosols. Using ultrahigh resolution mass spectrometry, more than 4000 individual molecular formulas were identified in non-urban aerosol water-soluble organic carbon. A significant fraction of the assigned molecular formulas were matched to assigned molecular formulas of laboratory generated secondary organic aerosols. AbstractWater-soluble organic carbon (WSOC) is a complex mixture of thousands of organic compounds which may have significant influence on the climate-relevant properties of atmospheric aerosols. An improved understanding of the molecular composition of WSOC is needed to evaluate the effect of aerosol composition upon aerosol physical properties. In this work, ultrahigh-resolution Fourier transform–ion cyclotron resonance mass spectrometry (FT-ICR MS) was used to characterise aerosol WSOC collected during the summer of 2010 at the Storm Peak Laboratory (3210 m ASL) near Steamboat Springs, CO. Approximately 4000 molecular formulas were assigned in the mass range of 100–800 Da after negative-ion electrospray ionisation and more than 50 % of them contained nitrogen or sulfur. The double bond equivalents (DBEs) of the molecular formulas were inversely proportional to the O : C ratio, despite a relatively constant H : C ratio of ~1.5. Despite the range of DBE values, the elemental ratios and the high number of oxygen atoms per formula indicate that a majority of the compounds are aliphatic to olefinic in nature. These trends indicate significant non-oxidative accretion reaction pathways for the formation of high molecular weight WSOC components. In addition, a significant number of molecular formulas assigned in this work matched those previously identified as secondary organic aerosol components of monoterpene and sesquiterpene ozonolysis.
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