Flexible supercapacitors with high power density, flexibility, and durability have shown enormous potential for smart electronics. Here, a continuous graphitic carbon nitride polyhedron assembly for flexible supercapacitor that is prepared by pyrolysis of carbon nanotubes wired zeolitic imidazolate framework‐8 (ZIF‐8) composites under nitrogen is reported. It exhibits a high specific capacitance of 426 F g−1 at current density of 1 A g−1 in 1 m H2SO4 and excellent stability over 10 000 cycles. The remarkable performance results from the continuous hierarchical structure with average pore size of 2.5 nm, high nitrogen‐doping level (17.82%), and large specific surface area (920 m2 g−1). Furthermore, a flexible supercapacitor is developed by constructing the assembly with interpenetrating polymer network electrolyte. Stemming from the synergistic effect of high‐performance electrode and highly ion‐conductive electrolyte, superior energy density of 59.40 Wh kg−1 at 1 A g−1 is achieved. The device maintains a stable energy supply under cyclic deformations, showing wide application in flexible and even wearable conditions. The work paves a new way for designing pliable electrode with excellent electronic and mechanic property for long‐lived flexible energy storage devices.
A new tundish design was investigated using both water model experiments and numerical simulations. The results show that the Reynolds Stress Model simulation results agree well with the Particle Image Velocimetry-measured results for water model experiments. A strong swirling flow in the Submerged Entry Nozzle (SEN) of the new tundish was successfully obtained, and the tangential velocity in the region near SEN inlet could reach a value of around 3.1 m/s. A high value of the shear stress was found to exist on the SEN wall, due to the strong swirling flow inside the SEN. This large shear stress leads to the dissipation of the rotational momentum of the steel flow. Thus, the maximum tangential velocity of the steel flow decreases from 3.1 m/s at around the SEN inlet to 2.2 m/s at a location close to the SEN outlet. In addition, the near-wall region has a high pressure, which is larger than the atmospheric pressure, due to the centrifugal effect. The calculated swirl number, with the value of around 1.6 at SEN inlet, illustrates that the current design can produce a similar strong swirling flow compared to the swirl blade method and the electromagnetic stirring method, while this is obtained by simply changing the steel flow path in tundish instead of using additional device to influence the flow.
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