Soft and conformable wearable electronics require stretchable semiconductors, but existing ones typically sacrifice charge transport mobility to achieve stretchability. We explore a concept based on the nanoconfinement of polymers to substantially improve the stretchability of polymer semiconductors, without affecting charge transport mobility. The increased polymer chain dynamics under nanoconfinement significantly reduces the modulus of the conjugated polymer and largely delays the onset of crack formation under strain. As a result, our fabricated semiconducting film can be stretched up to 100% strain without affecting mobility, retaining values comparable to that of amorphous silicon. The fully stretchable transistors exhibit high biaxial stretchability with minimal change in on current even when poked with a sharp object. We demonstrate a skinlike finger-wearable driver for a light-emitting diode.
Stretchable semiconducting polymers have been developed as a key component to enable skin-like wearable electronics, but their electrical performance must be improved to enable more advanced functionalities. Here, we report a solution processing approach that can achieve multi-scale ordering and alignment of conjugated polymers in stretchable semiconductors to substantially improve their charge carrier mobility. Using solution shearing with a patterned microtrench coating blade, macroscale alignment of conjugated-polymer nanostructures was achieved along the charge transport direction. In conjunction, the nanoscale spatial confinement aligns chain conformation and promotes short-range π-π ordering, significantly reducing the energetic barrier for charge carrier transport. As a result, the mobilities of stretchable conjugated-polymer films have been enhanced up to threefold and maintained under a strain up to 100%. This method may also serve as the basis for large-area manufacturing of stretchable semiconducting films, as demonstrated by the roll-to-roll coating of metre-scale films.
Recently, confinement of polymers with different geometries has become a research hotspot. Here, we report the dramatic deviation of glass transition behaviors of poly(methyl methacrylate) (PMMA) confined in cylindrical nanopores with diameter significantly larger than chain’s radius of gyration (R g ). Fast cooling a PMMA melt in the nanopores results in a glass with one single glass transition temperature (T g). But two distinct T gs are detected after slow cooling the melt. The deviation in T g could be as large as 45 K. This phenomenon is interpreted by a two-layer model. During vitrification under slow cooling two distinct layers are formed: a strongly constrained interfacial layer showing an increased T g as compared to that of the bulk polymer and a core with a decreased T g. By thermal annealing experiments, we find that these two T gs are inherently correlated. In addition, the deviation of T g for PMMA confined in nanopores reveals a dependence on molecular weight.
Organic semiconducting donor–acceptor polymers are promising candidates for stretchable electronics owing to their mechanical compliance. However, the effect of the electron‐donating thiophene group on the thermomechanical properties of conjugated polymers has not been carefully studied. Here, thin‐film mechanical properties are investigated for diketopyrrolopyrrole (DPP)‐based conjugated polymers with varying numbers of isolated thiophene moieties and sizes of fused thiophene rings in the polymer backbone. Interestingly, it is found that these thiophene units act as an antiplasticizer, where more isolated thiophene rings or bigger fused rings result in an increased glass transition temperature (Tg) of the polymer backbone, and consequently elastic modulus of the respective DPP polymers. Detailed morphological studies suggests that all samples show similar semicrystalline morphology. This antiplasticization effect also exists in para‐azaquinodimethane‐based conjugated polymers, indicating that this can be a general trend for various conjugated polymer systems. Using the knowledge gained above, a new DPP‐based polymer with increased alkyl side chain density through attaching alky chains to the thiophene unit is engineered. The new DPP polymer demonstrates a record low Tg, and 50% lower elastic modulus than a reference polymer without side‐chain decorated on the thiophene unit. This work provides a general design rule for making low‐Tg conjugated polymers for stretchable electronics.
The understanding of the structure-mechanical property relationship for semiconducting polymers is essential for the application of flexible organic electronics. Herein pseudo free-standing tensile testing, a technique that measures the mechanical property of thin films floating on the surface of water, is used to obtain the stress-strain behaviors of two semiconducting polymers, poly(3-hexylthiophene) (P3HT) and poly(2,5-bis(2-decyltetradecyl)-3,6-di(thiophen-2-yl)diketopyrrolo[3,4-c]pyrrole-1,4-dione-alt-thienovinylthiophene (DPP-TVT) donor-acceptor (D-A) polymer. To our surprise, DPP-TVT shows similar viscoelastic behavior to P3HT, despite DPP-TVT possessing a larger conjugated backbone and much higher charge carrier mobility. The viscoelastic behavior of these polymers is due to sub room temperature glass transition temperatures (T ), as shown by AC chip calorimetry. These results provide a comprehensive understanding of the viscoelastic properties of conjugated D-A polymers by thickness-dependent, strain rate dependent, hysteresis tests, and stress-relaxation tests, highlighting the importance of T for designing intrinsically stretchable conjugated polymers.
Mechanical failure of π-conjugated polymer thin films is unavoidable under cyclic loading conditions, due to intrinsic defects and poor resistance to crack propagation. Here, the first tear-resistant and roomtemperature self-healable semiconducting composites is presented, consisting of conjugated polymers and butyl rubber elastomers. This new composite displays both record-low elastic modulus (< 1 MPa) and ultra-high deformability with fracture strain above 800%. More importantly, failure behavior is not sensitive to precut notches under deformation. Autonomous self-healing at room temperature, both mechanical and electronic, is demonstrated through physical contact of two separate films. The composite film also shows device stability in the ambient environment over five months due to muchimproved barrier property to both oxygen and water. Butyl rubber is broadly applicable to various Ptype and N-type semiconducting polymers for fabricating self-healable electronics to provide new resilient electronics that mimic the tear resistance and healable property of human skin.
Semiconducting donor-acceptor (D-A) polymers have attracted considerable attention towards the application of organic electronic and optoelectronic devices. However, a rational design rule for making semiconducting polymers with desired thermal and mechanical properties is currently lacking, which greatly limits the development of new polymers for advanced applications.Here, polydiketopyrrolopyrrole (PDPP)-based D-A polymers with varied alkyl side-chain lengths and backbone moieties are systematically designed, followed by investigating their thermal and thin film mechanical responses. The experimental results show a reduction in both elastic modulus and glass transition temperature (T g ) with increasing side-chain length, which is further verified through coarse-grained molecular dynamics (CG-MD) simulations. Informed from experimental results, a mass-per-flexible bond model is developed to capture such observation through a linear This article is protected by copyright. All rights reserved. 3 correlation between T g and polymer chain flexibility. Using this model, a wide range of backbone T g over 80 C and elastic modulus over 400 MPa can be predicted for PDPP-based polymers. This study highlights the important role of side-chain structure in influencing the thermomechanical performance of conjugated polymers, and provides an effective strategy to design and predict T g and modulus of future new D-A polymers.) The synthesis part was financially supported by the Natural Sciences and Engineering Research Council of Canada (NSERC) through a Discovery Grant (RGPIN-2017-06611), and by the Canadian Foundation for Innovation (CFI). M. U. O. thanks NSERC for a doctoral scholarship.
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