Purpose This paper aims to investigate the deposited structure and mechanical performance of printed materials obtained during initial development of the Big Area Additive Manufacturing (BAAM) system at Oak Ridge National Laboratory. Issues unique to large-scale polymer deposition are identified and presented to reduce the learning curve for the development of similar systems. Design/methodology/approach Although the BAAM’s individual extruded bead is 10-20× larger (∼9 mm) than the typical small-scale systems, the overall characteristics of the deposited material are very similar. This study relates the structure of BAAM materials to the material composition, deposition parameters and resulting mechanical performance. Findings Materials investigated during initial trials are suitable for stiffness-limited applications. The strength of printed materials can be significantly reduced by voids and imperfect fusion between layers. Deposited material was found to have voids between adjacent beads and micro-porosity within a given bead. Failure generally occurs at interfaces between adjacent beads and successive layers, indicating imperfect contact area and polymer fusion. Practical implications The incorporation of second-phase reinforcement in printed materials can significantly improve stiffness but can result in notable anisotropy that needs to be accounted for in the design of BAAM-printed structures. Originality/value This initial evaluation of BAAM-deposited structures and mechanical performance will guide the current research effort for improving interlaminar strength and process control.

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As a result of recent increases in fuel prices and the growing number of accident fatalities, the two major concerns of the automotive industry and their customers are now occupant safety and fuel economy [1,2]. Increasing the amount of energy and optimizing the manner in which energy is absorbed within vehicle crush zones can improve occupant survivability in the event of a crash, while fuel economy is improved through a reduction in weight.Axial crush tests were conducted on tubular specimens of Carbon/Epoxy (Toray T700/G83C) and Glass/Polypropylene (Twintex). This paper presents results from the tests conducted at quasi-static rates at Deakin University, Victoria Australia, and intermediate rate tests performed at the Oak Ridge National Laboratory, Tennessee USA.The quasi-static tests were conducted at 10mm/min (1.67x10-4m/s) using 5 different forms of initiation. Tests at intermediate rates were performed at speeds of 0.25m/s, 0.5m/s, 0.75m/s 1m/s, 2m/s and 4m/s. Quasi-static tests of tubular specimens showed high specific energy absorption (SEA) values with 86 kJ/kg for Carbon/Epoxy specimens. The SEA of the Glass/Polypropylene specimens was measured to be 29 kJ/kg.Recently, automotive manufacturers have been under increasing legislative

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The crashworthiness characteristics of rectangular tubes made from a carbon-fiber reinforced hybrid-polymeric matrix (CHMC) composite were investigated using quasistatic and impact crush tests. The hybrid matrix formulation of the CHMC was created by combining an epoxy-based thermosetting polymer with a lightly crosslinked polyurea elastomer at various cure-time intervals and volumetric ratios. The load-displacement responses of both CHMC and carbon-fiber reinforced epoxy (CF/epoxy) specimens were obtained under various crushing speeds; and crashworthiness parameters, such as the average crushing force and specific energy absorption (SEA), were calculated using subsequent load-displacement relationships. The CHMC maintained a high level of structural integrity and post-crush performance, relative to traditional CF/epoxy. The influence of the curing time and volumetric ratios of the polyurea/ epoxy dual-hybridized matrix system on the crashworthiness parameters was also investigated. The results reveal that the load carrying capacity and total energy absorption tend to increase with greater polyurea thickness and lower elapsed reaction curing time of the epoxy although this is typically a function of the loading rate. Finally, the mechanism by which the CHMC provides increased damage tolerance was also investigated using scanning electron microscopy (SEM).

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Galling is a severe form of surface damage in metals and alloys that typically arises under relatively high normal force and low sliding speed and in the absence of effective lubrication. It can lead to macroscopic surface roughening and seizure. The occurrence of galling can be especially problematic in hightemperature applications like diesel engine exhaust gas recirculation system components and adjustable turbocharger vanes, because suitable lubricants may not be available, moisture desorption promotes increased adhesion, and the yield strength of metals decreases with temperature. Oxidation can counteract these effects to some extent by forming lubricative oxide films. Two methods to improve the galling resistance of titanium alloy Ti-6Al-4V were investigated: (a) applying an oxygen diffusion treatment and (b) creating a metal-matrix composite with TiB 2 using a high-intensity infrared heating source. A new oscillating three-pin-on-flat, high-temperature test method was developed and used to characterize galling behavior relative to a cobaltbased alloy (Stellite 6B, HP Alloys, Windfall, IN). The magnitude of the oscillating torque, the surface roughness, and observations of surface damage were used as measures of galling resistance. Due to the formation of lubricative oxide films, the galling resistance of the Ti alloy at 485 • C, even nontreated, was considerably better than it was at room temperature. The infrared (IR)-formed composite displayed reduced surface damage and lower torque than the substrate titanium alloy.