The effective removal of nitrogen compounds from wastewater has become a critical issue for treatment plants as the awareness of their negative impact on the environment increased. Autotrophic nitrogen removal has become an interesting alternative to the more conventional heterotrophic processes, as it eliminates the need for an organic carbon addition to the source water and reduces biomass yields. Gas transfer membrane biofilm reactors (MBfR) for nitrification and hydrogen driven denitrification are of special interest as they combine membrane diffusers and biofilms, provide an efficient supply of necessary electron donor for autotrophic removal of ammonia and nitrate, extend solids retention times and retain biomass within the reactor. Subsequently, a wide range of MBfR, which vary based on the type of membrane material and membrane module configuration, are being tested for this purpose. This paper reviews the research to date and also discusses the challenges that still lay ahead before MBfR can be used at treatment plants.
A material flux analysis on sulfur (S), phosphorus (P), aluminum (Al), and iron (Fe) was conducted for two WWTPs (Galt and Kitchener) to evaluate the potential of coagulants that are employed for phosphorus control to reduce hydrogen sulfide (H2S) emissions in the biogas from anaerobic digestion. It was found that while the Galt WWTP receives higher concentrations of S in the raw wastewater than the Kitchener WWTP, this had only a modest impact on the speciation of S entering anaerobic digestion. At both plants, only 2%–4% of influent S entered the digesters. The presence of Fe in the sludge stream was found to cause S, that is released by volatile solid destruction and sulfate (SO42-SO42-) reduction, to become particulate‐bound. A dosage of 1.1 mg/L of Fe into the raw wastewater (11% of the Fe dosed for P control) was sufficient for sulfide (S2‐) control. Transitioning the Galt WWTP from Al to Fe dosing for P control had no significant impact on effluent P concentrations and resulted in a substantial reduction in the biogas H2S concentration. An additional secondary benefit was an increase in the solid content of the dewatered cake.
Practitioner points
Material flux analyses can be employed to gain insight into the fate of key elements contributing to biogas quality.
The use of iron for phosphorous control can effectively control H2S in anaerobic biogas.
Conversion from Al2(SO4)3 to FeSO4 dosing for P control resulted in increased solid content of centrifuged biosolids.
Although many studies have examined how improvements in wastewater treatment impact river nutrient concentrations and loads, there has been much less focus on measuring river metabolism to evaluate the wider aquatic ecosystem benefits of reducing nutrient inputs to rivers. The objectives of this study were to evaluate the effects of enhanced wastewater treatment (nitrification) on river metabolism in the Grand River, Canada's largest river draining into Lake Erie. Metabolic fingerprints and regimes (calculated from high-frequency dissolved oxygen [DO] measurements) were used to visualize whole-river ecosystem functional responses to these wastewater treatment upgrades. There was a 60% reduction in ecosystem respiration during summer, in response to reductions in effluent total ammonia inputs, causing a shift from net heterotrophy to net autotrophy, and contraction of river metabolic fingerprints. This resulted in major improvements in summer DO concentrations, with reductions in the percentage of days during summer that DO minima fell below waterquality guidelines for protection of aquatic early life stages, from 88% to ≤16%. The results also point to potential cascading impacts on coupled phosphorus and nitrogen cycles, which may generate further improvements in river water quality. During the summer, high rates of river metabolism and nutrient retention may result in measured water-column nutrient concentrations potentially underestimating nutrient pressures. This study also demonstrates the value of combining river metabolism with nutrient monitoring for a more holistic understanding of the role of nutrients in river ecosystem health and function.
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