We synthesized ZnO nano-micro structures, including microrods, nanosheets, a nanosheet selfassembled hollow sphere (NSHS), and a hollow hierarchical aggregate (HHA) by changing the concentration of trisodium citrate in a hydrothermal process. The NSHS was formed by the self-assembly of 2D nanosheets on the surface of a formaldehyde bubble, while the HHA was obtained by the self-assembly and hierarchical arrangement of NSHS. The photocatalytic activities of the ZnO structures were evaluated from the degradation of methylene blue under visible and black light irradiation. The NSHS showed better photocatalytic performance due to its excellent photon absorbance, low defect density and low emission quantum yield compared with the HHA. Furthermore, the size and number of the 2D nanosheets hydrothermally grown on the NSHS bubble template were controlled by changing the growth temperature.
Ibuprofen contamination from water sources has been increasingly alarming due to its environmentally accumulative retention; however, the strategies for ibuprofen-containing water treatment are still an enormous challenge. Herein, we described the utilization of metal-organic frameworks MIL-53(Fe) (MIL = Materials of Institute Lavoisier) for the adsorption of ibuprofen in synthetic solution. Firstly, the MIL-53(Fe) was solvothemally synthesized and then characterized using the X-ray diffraction and Fourier-transform infrared spectroscopy techniques. The optimization of ibuprofen adsorption over MIL-53(Fe) was performed with three independent variables including ibuprofen concentration (1.6–18.4 mg/L), adsorbent dosage (0.16–1.84 g/L), and pH (2.6–9.4) according to the experimental design from response surface methodology. Under the optimized conditions, more than 80% of ibuprofen could be eliminated from water, indicating the promising potential of the MIL-53(Fe) material for treatment of this drug. Kinetic and isotherm models also were used to elucidate the chemisorption and monolayer behavior mechanisms of ibuprofen over MIL-53(Fe).
This study is devoted to the modeling and simulation of uncertainties in the constitutive elastic properties of material constituting a circular column under axial compression. To this aim, a probabilistic model dedicated to the construction of positive-definite random elasticity matrices was first used, involving two stochastic parameters: the mean value and a dispersion parameter. In order to compute the nonlinear effects between load and lateral deflection for the buckling problem of the column, a finite element framework combining a Newton-Raphson solver was developed. The finite element tool was validated by comparing the as-obtained critical buckling loads with those from Euler’s formula at zero-fluctuation of the elasticity matrix. Three levels of fluctuations of material uncertainties were then propagated through the validated finite element tool using the probabilistic method as a stochastic solver. Results showed that uncertain material properties considerably influenced the buckling behavior of columns under axial loading. The coefficient of variation of a critical buckling load over 500 realizations were 15.477%, 26.713% and 41.555% when applying dispersion parameters of 0.3, 0.5 and 0.7, respectively. The 95% confidence intervals of column buckling response were finally given. The methodology of modeling presented in this paper is a potential candidate for accounting material uncertainties with some instabilities of structural elements under compression.
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