In megabar shock waves, materials compress and undergo a phase transition to a dense charged-particle system that is dominated by strong correlations and quantum effects. This complex state, known as warm dense matter, exists in planetary interiors and many laboratory experiments (for example, during high-power laser interactions with solids or the compression phase of inertial confinement fusion implosions). Here, we apply record peak brightness X-rays at the Linac Coherent Light Source to resolve ionic interactions at atomic (ångström) scale lengths and to determine their physical properties. Our in situ measurements characterize the compressed lattice and resolve the transition to warm dense matter, demonstrating that short-range repulsion between ions must be accounted for to obtain accurate structure factor and equation of state data. In addition, the unique properties of the X-ray laser provide plasmon spectra that yield the temperature and density with unprecedented precision at micrometre-scale resolution in dynamic compression experiments. M aterials exposed to high pressures of 1 Mbar and above have recently been the subject of increased attention due to their importance for the physics of planetary formation 1-3 , for material science 4 and for inertial confinement fusion research 5 . The behaviour of shock-compressed aluminium is of particular interest because it has been proposed as a standard for shock-wave experiments 6 and is widely used for equation-of-state 7,8 and warm dense matter (WDM) 9,10 studies. At room temperature, aluminium has three delocalized electrons, so it provides a prototype for an ideal electron fluid. As temperatures and pressures increase, compressing and breaking ionic lattice bonds, strong ionic forces remain, resulting in significant deviations from a simple fluid.Simulations using density functional theory coupled to manyparticle molecular dynamics (DFT-MD) have evolved into an ab initio tool to explore this regime of high-pressure physics 11,12 . To date, these simulations have been used to predict physical properties derived from optical observations of particle and shock velocities. Studies of structural properties that are sensitive to many-particle electron-ion and ion-ion interaction physics 13 have been challenging 14 , although recent progress has been made using X-ray absorption spectroscopy 15,16 . Early experiments on fourth-generation light sources 17 have made use of X-ray diffraction and measured the structural evolution from elastic to plastic states 18 . However, pressures in the Mbar regime, as required for melting many solids, have only recently become available at the Matter in Extreme Conditions (MEC) instrument at the Linac Coherent Light Source (LCLS).Here we visualize, for the first time, the evolution of compressed matter across the melting line and the coexistence regime into a WDM state. The combination of high-power optical lasers and the X-ray beam at MEC provides high-resolution X-ray scattering at multi-Mbar pressures. Our data provide the io...

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Temperature equilibration in dense, strongly coupled plasmas has been investigated without most of the usual simplifying assumptions. A quantum kinetic approach is used that accounts for strong electron-ion collisions through an exact T-matrix treatment of the scattering cross section using a screened interaction. Our results reveal the accuracy of the usual Spitzer formula for Coulomb logarithms larger than about three. Moreover, a simple model based on hyperbolic orbits yields surprisingly accurate results. We also have included equation of state effects to describe realistic plasmas.

The shock-induced transition from graphite to diamond has been of great scientific and technological interest since the discovery of microscopic diamonds in remnants of explosively driven graphite. Furthermore, shock synthesis of diamond and lonsdaleite, a speculative hexagonal carbon polymorph with unique hardness, is expected to happen during violent meteor impacts. Here, we show unprecedented in situ X-ray diffraction measurements of diamond formation on nanosecond timescales by shock compression of pyrolytic as well as polycrystalline graphite to pressures from 19 GPa up to 228 GPa. While we observe the transition to diamond starting at 50 GPa for both pyrolytic and polycrystalline graphite, we also record the direct formation of lonsdaleite above 170 GPa for pyrolytic samples only. Our experiment provides new insights into the processes of the shock-induced transition from graphite to diamond and uniquely resolves the dynamics that explain the main natural occurrence of the lonsdaleite crystal structure being close to meteor impact sites.

The femtosecond dynamics of the electrons in aluminum after an intense extreme ultraviolet pulse is investigated by Monte Carlo simulations. Transient distributions of the conduction band electrons show an almost thermalized, low-energy part and a high-energy tail. Constructing emission spectra from these data, we find excellent agreement with measurements. The radiative decay mainly reflects the colder part of the distribution, whereas the highly excited electrons dominate the bremsstrahlung spectrum. For the latter, we also find good agreement between predicted and measured energy scales.

A quantum kinetic approach for the energy relaxation in strongly coupled plasmas with different electron and ion temperatures is presented. Based on the density operator formalism, we derive a balance equation for the energies of electrons and ions connecting kinetic, correlation, and exchange energies with a quite general expression for the electron-ion energy-transfer rate. The latter is given in terms of the correlation function of density fluctuations which allows for a derivation of increasingly realistic approximation schemes including a coupled-mode expression. The equilibration of the contributions of the total energy including the species temperatures in dense hydrogen and beryllium relevant for inertial confinement fusion is investigated as an example.

We develop the theory for light scattering as a diagnostic method for plasmas in nonequilibrium states. We show how well-known nonequilibrium features, like beam acoustic modes, arise in the spectra. The analysis of an experiment with strongly driven electrons demonstrates the abilities of the new approach; we find qualitatively different scattering spectra for different times and excellent agreement with the experimental data after time integration. Finally, an analysis of data from dense beryllium suggests that an energetic electron component exists in this experiment as well.

Detailed measurements of the electron densities, temperatures, and ionization states of compressed CH shells approaching pressures of 50 MBar have been achieved with spectrally resolved x-ray scattering. Laser-produced 9 keV x-rays probe the plasma during the transient state of threeshock-coalescence. High signal-to-noise x-ray scattering spectra show direct evidence of continuum depression in highly degenerate warm dense matter states with electron densities ne > 10 24 cm −3 . The measured densities and temperatures agree well with radiation-hydrodynamic modeling when accounting for continuum lowering in calculations that employ detailed configuration accounting.