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Dynamics of bacterial communities and nitrogen metabolism genes in a full-scale WWTP as revealed by Illumina sequencing and PICRUSt.

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A cobalt/POL-PPh catalyzed ( E)-selective hydrosilylation of alkynes with PhSiH has been developed for the synthesis of ( E)-β-vinylsilanes with high regio- and stereoselectivity and wide functional group tolerance. It is the first report of using porous organic polymer as a recyclable regio- and stereoselective and efficient ligand in hydrosilylation reactions in which the polymer could be recycled numerous times in a continuous flow system without loss of activity and selectivity. The earth-abundant base-metal catalyst, coordinated by heterogeneous recyclable ligand, shows promise for industrial application.