A polyvinyl chloride (PVC) membrane based Pr(III) selective electrode was constructed using 1,6,7,12-tetramine-2,5,8,11-tetraoxo-1(12),6(7)-di(biphenyl)dodecane (TATODBDD) as a neutral carrier. The sensor exhibits a Nernstian response for Pr(III) ions, a wide concentration range of 3.9×10-7 -1.0×10 -1 mol/L with a detection limit of 5.0×10 -8 mol/L and slope of 19.5 mV/decade. The developed sensor revealed relatively good selectivity and high sensitivity for Pr(III) ions over the other lanthanide ions. The potentiometric response of the sensor is independent in the pH range 2.9-9.5. The advantages of sensor are low resistance, very fast response time (<10 s) with good selectivity. This sensor can be used up to 6 weeks without any divergences in potential response.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.