Heterogeneous ice nucleating particle (INP) concentrations are reported for a site on the eastern margin of Beijing, China, during the period 4 May to 4 June 2018. INP concentrations were measured continuously at −20, −25, and −30 °C in a repeating cycle by a newly developed, automated continuous flow diffusion chamber, and reached concentrations as high as 2800 sL−1 during dust‐impacted periods. Study average concentrations were 70 ± 70, 230 ± 290, and 430 ± 500 sL−1 at −20, −25, and −30 °C. There was no clear relationship between pollution periods, identified based on fine‐mode particle concentration increases, and INP concentrations or characteristics. Other anthropogenic emissions, such as non‐combustion industrial or agricultural activities play an unresolved role.

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The size-resolved properties of atmospheric black carbon (BC) importantly determine its absorption capacity and cloud condensation nuclei (CCN) ability. This study reports comprehensive vertical profiles of BC size-related properties over the Beijing area (BJ) and Continental Europe (CE). BC mass loadings over CE were in the range of clean background over BJ. For both planetary boundary layer (PBL) and lower free troposphere, the BC mass median core diameter over BJ during the cold season was 0.21 ± 0.02 μm, larger than the warm season over BJ and CE (0.18 ± 0.01 μm), which may reflect seasonal differences in emissions. The BC coatings were positively correlated with the pollution level, with background BC having a smaller coated count median diameter (0.19 ± 0.01 μm). The modeled absorption enhancement (E abs) due to coatings was 1.23 ± 0.14 for the background but in the PBL following a linear expression (E abs = 0.13 × MassBC,surface + 1.26). The CCN ability of BC was significantly enhanced in the polluted PBL, due to both enlarged size and increased hygroscopicity. In polluted BJ at predicted supersaturations, ∼0.08% half of the BC number could be activated, whereas the cleaner environment needs ∼0.14%. The results here suggest that the highly coated and absorbing BC can be efficiently incorporated into clouds and can exert important indirect radiative impacts over the polluted East Asia region.

Wet scavenging of black carbon (BC) has been subject to large uncertainty, which importantly determines its atmospheric lifetime and indirect forcing impact on cloud microphysics. This study reveals the complex BC‐hydrometeor interactions in mixed‐phase clouds via single particle measurements in the real‐world environment, by capturing precipitation processes throughout cloud formation, cold rain/graupel, and subsequent snow events at a mountain site influenced by anthropogenic sources in wintertime. We found highly efficient BC wet scavenging during cloud formation, with large and thickly coated BC preferentially incorporated into droplets. During snow processes, BC core sizes in the interstitial phase steadily increased. A mechanism was proposed whereby the BC mass within each droplet was accumulated through droplet collision, leading to larger BC cores, which were then released back to the interstitial air through the Wegener‐Bergeron‐Findeisen processes when ice dominated. These results provide fundamental basis for constraining BC wet scavenging.

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34Urbanization modifies atmospheric energy and moisture balances, forming distinct 35 features, e.g., urban heat islands (UHIs) and enhanced or decreased precipitation. 36These produce significant challenges to science and society, including rapid and incudes complex topography with mountains, plains, and coastal areas (Fig. 1a), and 261 seven of the 10 most polluted Chinese cities, with 40% of days during 2013 (mostly in 262 winter) having "very hazardous" air quality (CMEP 2014 adaptation, air quality, planning, and emergency-response management. 298The critical science needed to achieve these goals was identified as increased WUQ), and one rural (SDZ) tower (all PBL observational sites are shown in Fig. 1). 335Other operational PBL sensors ( conditions. Photos of a selection of these instruments and sites are shown in Fig. 2. flown over pre-approved flight paths (Fig. 1) at altitudes from 600 to 3 600 m (at 300 357 m intervals). The aircraft is equipped with atmospheric gas and aerosol instrumenta- Additional observation data (e.g., weather radar, aircraft, and lightning) will be added. BTH area centered on Beijing (a somewhat larger area than in Fig. 1a). 439Additional details on all of these steps are provided by Zhang et al. (2017a (Fig. 1) were used to show that the dominant linear relationship between * and also 494 exists over urban canopies. The strong wind shear from the rough urban surfaces produces 495 turbulence in near neutral urban stability conditions, shown by Bornstein 1968 to exist over 496 NYC, as stable boundary layers over urban canopies are thus hard to maintain. The role of 497 surface roughness on turbulent mixing is also reflected in the increasing slope (Fig. 4) Table 4a shows the average midday (1000-1400 LST) radiative and energy fluxes 515Although MIY has higher outgoing longwave radiation, the net all-wave radiations 516 are nearly equal. Significant differences existed, however, in the surface energy 517 partitions, as IAP has smaller turbulent sensible and latent heat fluxes, and thus a 518 larger (estimated) residual heat storage. Another contributing factor to urban heat 519 storage is its anthropogenic heat flux source (discussed below). 520Daily mean Bowen ratios (ratio of turbulent sensible to latent-heat flux; Table 4b Normalized relative backscatter (NRB) data from two MPL lidar (in a vertical to 545 zenith scan mode) were also used to concurrently estimate midday PBL heights on 11 546August 2015 from 1250-1402 LST, both alone a mobile route (Fig. 1b) and at a fixed 547 site (adjacent to the urban IAP tower). As MPL instruments cannot be absolutely Beijing and fluxes from the 140-m level of the IAP tower (Fig. 1b). The modeling 574 period was 4-11 July 2015, which included dry (6 th -11 th ) and wet (4 th -5 th ) days. 575Results show major improvement for daytime "total" sensible plus latent heat flux 576 values ( Fig. 7a and b), although the timing of its peak was about 2 h too late. The 577 increased latent heat flux during the EC simulation (ac...

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