Electrothermal materials transform electric energy into heat due to the Joule effect. To date, resistive wires made of heavy metal alloys have primarily been used as the heat source in many appliances surrounding us. Recent discoveries in the field of carbon nanostructures revealed that they can offer a spectrum of advantages over the traditional materials. We review the production methods of thin films composed of carbon nanotubes or graphene and depict how they can be used as conductive coatings for electrothermal applications. We screen all reports from the field up to now and highlight the features of designed nanoheaters. A particular focus is placed on the analysis of general findings of how to tune their electrothermal properties, why carbon nanostructure devices operate the way they do and in what aspects they are superior to the currently available materials on the market.
Depending on their structure and order (individual, films, bundled, buckypapers, etc.), carbon nanotubes (CNTs) demonstrate different values of thermal conductivity, from the level of thermal insulation with the thermal conductivity of 0.1 W/mK to such high values as 6600 W/mK. This review article concentrates on analyzing the articles on thermal conductivity of CNT networks. It describes various measurement methods, such as the 3-x method, bolometric, steady-state method and their variations, hot-disk method, laser flash analysis, thermoreflectance method and Raman spectroscopy, and summarizes the results obtained using those techniques. The article provides the main factors affecting the value of thermal conductivity, such as CNT density, number of defects in their structure, CNT ordering within arrays, direction of measurement in relation to their length, temperature of measurement and type of CNTs. The practical methods of using CNT networks and the potential directions of future research in that scope were also described.
The electronic properties of carbon nanostructures such as carbon nanotubes (CNTs) or graphene can easily be tuned by the action of various doping agents. We present an experimental study and numerical analysis of how and why metallic and semiconductive CNTs can be p-doped by exposing them to two interhalogens: iodine monochloride and iodine monobromide. Simple application of these compounds was found to reduce the electrical resistance by as much as 2/3 without causing any unfavorable chemical modification, which could disrupt the highly conductive network of sp carbon atoms. To gain better insight into the underlying mechanism of the observed experimental results, we provide a first principles indication of how interhalogens interact with model metallic (5,5) and semiconductive (10,0) CNTs.
The direct-spinning method of creation of CNT macroassemblies has received a lot of attention because of its simplicity to produce high-performance material without apparent limits to its size. CNT fibers or films have shown unparalleled properties and opened new areas of research and commercial development. The process designed more than a decade ago has already given interesting information about the basic science of nanomaterials, which in parallel led to the creation of the first prototypes with high potential of implementation in everyday life. Because of this, there has been growing interest in this technique with research articles coming into view from all around the world on a frequent basis. This review aims to summarize all the progress made in the direct-spinning process on a spectrum of fronts ranging from the study of complex synthesis parameters, material properties to its viable applications. The strong and weak points of the "Cambridge process" are carefully evaluated to put forward what challenges are most pressing. The future overlook puts the state of the art into perspective and suggests the prospective research directions.
Single-walled carbon nanotubes (SWCNTs) have revealed an extraordinary potential for photonics. However, the scarcity of convenient methods to control chirality and inherently low quantum yield hamper their implementation in the...
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