Industrial emissions are of major concern, especially in developing countries. Hence, there is a need for studies that investigate the trends in industrial emissions in these countries. The purpose of this study is to discuss trends in industrial emissions in Kazakhstan and the air pollution level in its industrial cities. Data on emission limit values from the permitting documents of twenty-one power plants and nine metallurgical enterprises of Kazakhstan were analyzed. Eight cities (out of fourteen) had a “high” level of atmospheric air pollution according to the Air Pollution Index in 2019. Most of the considered enterprises increased their emission limit values compared to previous permitting period. At some cities there is a lack of monitoring stations, indicating the need for improving the spatial coverage of the air quality monitoring network in the industrial cities of Kazakhstan. The location of industrial plants far outside the cities could reduce the exposure of the urban population to air pollution. Kazakhstan urgently needs to adopt stringent emissions standards for coal-fired power plants and heavy industrial plants. The national air quality standards and definitions of air pollutants need to be updated based on the latest scientific knowledge.
To slow the spread of COVID-19, the state of emergency was announced in Kazakhstan on March 16, 2020. Ust-Kamenogorsk instituted COVID-19 lockdown measures on April 2, 2020. The restrictions reduced the flow of traffic in the city, but did not have a major impact on the large industries and power plants. In the areas with a complex profile of emission sources, traffic restriction measures alone may hardly tackle serious air pollution. This natural experiment allowed to test how reduction in transport movement affects air quality in Ust-Kamenogorsk, as there is a tendency to hold transport as being a major cause of air pollution in Ust-Kamenogorsk.
Air quality issues still affect the quality of life for people in industrialised cities around the world. The investigations should include the identification of the sources of the pollution and its distribution in space and time. This work is the first attempt to perform identification of the sources of pollution in Ust-Kamenogorsk city in Kazakhstan. Analysis of retrospective data (including ten variables (TSP, SO2, CO, NO2, phenol, HF, HCl, H2SO4, formaldehyde, H2S) from five monitoring stations for the period 2017–2021) using multivariate statistical methods and hierarchical cluster analysis has been performed to assess spatiotemporal patterns of air quality of the city. The results indicate that the contamination patterns can be grouped into two categories: cold and warm seasons. The study revealed the dangerous concentrations of NO2 and SO2 exceeded the limits by 2–3 and 1.5–2 times, independently of the seasonality. Averaged concentrations of TSP slightly exceeded the established limits for the most industrialised part of the city. Concentrations of HF and formaldehyde significantly rose during the cold seasons compared to the warm seasons. Other chemical parameters significantly depend on the seasonality and locations of the sampling points. The major reason for air pollution is twofold—the use of a burnt-coal throughout the year for electricity and heat generation (especially during the cold seasons) and the high density of the heavy metallurgy industry in the city. The principal component analysis confirms a high loading of industrial sources of air pollution on both spatial and seasonal dimensions.
The composition and technology for the production of semi-dry ceramic bricks using a nanostructured complex sorbent based on bentonite clay of the 11th horizon of the Tagan deposit of the Republic of Kazakhstan and basalt fiber (gabbro-diabase) of the Karauzek deposit of East Kazakhstan have been developed. The characteristics, chemical composition, and structure of the spent sorbent are given based on electron microscopic and X-ray phase analyses. A number of physical and mechanical parameters have been studied to evaluate the spent sorbent as a raw material for the production of ceramic products. The microstructures of fired ceramic samples with loam and spent sorbent have been studied, and the features of their structure have been revealed. The environmental safety of waste sorbents utilization by extraction in acidic, alkaline, and neutral media with the determination of the content of chromium, zinc, and iron ions has been studied. Experimentally obtained data indicate an insignificant concentration of chromium and zinc ions, not exceeding 3.5 µg/L. Relatively high concentrations of iron ions in ceramic bricks are associated with their high content in the feedstock and in the spent sorbent. It has been established that the introduction of the spent sorbent in the amount of 25% of the total mass increases the strength of the final product from 10.8 to 15.8 MPa, which corresponds to the M125 ceramic brick grade.
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