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The present study aim to assess the effect of phosphate and urea fertilizers on the physicochemical properties, pH and electrical conductivity (EC) of the soil. The effect of these fertilizers on cation exchange capacity (CEC), organic matter (OM), and the possibility of contamination with heavy metals (HM) (Cr, Cu, Cd, Mn, Zn, Ni, Fe, and Pb) were studied on the soils of Alshati agricultural project at different seasons after forty years of fertilization. Uncultivated soil samples were also analyzed for comparison and considered as reference. Mean values of soil pH, EC, CEC, and OM ranged between 6.88-7.32, 0.14–0.26 μS/cm, 2.95–4.19 Cmol/kg and 0.49–0.53%, respectively, in all seasons. Concentrations of HMs were 9.50–38.38, 0.0–2.05, 0.0–0.47, 0.0–29.81, 0.0–13.85, 2.83–25.95 and 104–512.20 mg/kg respectively, for Cr, Cu, Cd, Mn, Zn, Ni and Fe. The concentrations of the HMs in the soil were found to be vary significantly with the seasons (winter, spring, summer, and autumn). However, no traces of Pb was found in the soil samples. The result showed a significant correlation between, pH, EC, CEC, OM and HM content of the soil. The geochemical index of contamination shows that there was no contamination with Cu, Cd, Zn, Pb, Cr, Mn, Ni, and Fe.

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Petroleum-derived plastics dominate currently used plastic materials. These plastics are derived from finite fossil carbon sources and were not designed for recycling or biodegradation. With the ever-increasing quantities of plastic wastes entering landfills and polluting our environment, there is an urgent need for fundamental change. One component to that change is developing cost-effective plastics derived from readily renewable resources that offer chemical or biological recycling and can be designed to have properties that not only allow the replacement of current plastics but also offer new application opportunities. Polyhydroxyalkanoates (PHAs) remain a promising candidate for commodity bioplastic production, despite the many decades of efforts by academicians and industrial scientists that have not yet achieved that goal. This article focuses on defining obstacles and solutions to overcome cost-performance metrics that are not sufficiently competitive with current commodity thermoplastics. To that end, this review describes various process innovations that build on fed-batch and semi-continuous modes of operation as well as methods that lead to high cell density cultivations. Also, we discuss work to move from costly to lower cost substrates such as lignocellulose-derived hydrolysates, metabolic engineering of organisms that provide higher substrate conversion rates, the potential of halophiles to provide low-cost platforms in non-sterile environments for PHA formation, and work that uses mixed culture strategies to overcome obstacles of using waste substrates. We also describe historical problems and potential solutions to downstream processing for PHA isolation that, along with feedstock costs, have been an Achilles heel towards the realization of cost-efficient processes. Finally, future directions for efficient PHA production and relevant structural variations are discussed.