This study presents a systematic
investigation of bilgewater emulsion
characteristics using various in situ analytical
methods, while assessing the effect of environmental parameters [e.g., ionic strength, suspended solids (SS), and temperature]
on emulsion destabilization. The stabilizing properties of three emulsifiers
[Triton X-100, B&B 3100, and sodium dodecyl sulfate (SDS)] were
evaluated under various conditions over 5 days. Time-course visual
observation, relative oil separation, droplet size distribution, and
grayscale intensity profiles were used for the physical characterization
of the emulsion samples. In particular, the grayscale intensity was
found to be a useful technique for the rapid detection of emulsion
separation using simple image analysis. Major findings on bilgewater
emulsion stability in this study are as follows: (1) emulsion stability
decreased with NaCl (ionic strength) addition and temperature increase,
resulting in higher oil separation, (2) emulsions stabilized with
B&B 3100 (commercial cleaner) were more stable than Triton X-100
and SDS (neat surfactants) at the equivalent critical micelle concentration,
and (3) SSs particle size larger than the initial droplet size could
promote the formation of larger emulsion droplets, thus increasing
oil coalescence as corroborated by visual observation. Overall, this
study highlighted a defined set of easy and rapid emulsion analytical
methods, which provided significant information regarding bilgewater
emulsion stability. These techniques demonstrated to be a rapid solution
for the in situ characterization of bilgewater emulsions
primarily in offshore locations lacking sophisticated equipment. These
methods can be used for further investigation of other cleaning products
found on ships and actual bilgewater samples to assist in the appropriate
bilgewater treatment and management.
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