Combined electrical, optical, and spectroscopic measurements have been used to determine the total flux, ion flux, particle flux, and neutral atom flux emitted from the cathode spot region of a copper vacuum arc of 80 A total current and 2-sec duration. It is found that the cathode erosion products consist predominantly of ions and particles, the emission of neutral atomic flux from the cathode being less than 1% of the total flux. The total and particle flux distributions are peaked in the direction of the cathode plane, whereas the ion-flux distribution is forward peaked. However, both ions and particles are detected in the cathode shadow, a result which is contrary to the hypothesis of purely collisionless transport of cathode erosion products. The neutral atom density measurements are consistent with a model assuming the source of the vapor to be evaporation in flight from the hot particles emitted from the cathode spot region. The size distribution of the particles has a maximum for particles of diameter in the range 0–1 μ.
The use of the multitemperature Saha equation (MSE) of Prigogine1 and Patapov2 for calculating particle concentrations in plasmas is shown to be an invalid procedure. Errors greater than one order of magnitude in the electron density in high-pressure argon and nitrogen electric arc plasmas can be easily incurred by using the multitemperature Saha equation. The alternative kinetic method for calculating concentrations is shown to be based on firm concepts. Simpliying procedures and computational techniques for calculating concentrations with the kinetic method are illustrated with examples.
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