The results of the use of thermally modified kieselguhr sludge from the production of vegetable oils (TKSH500) of the initial and activated with a 30 % solution of nitric acid (TKSH500k) and 1M sodium hydroxide solution (TKSH500sh) for purification of model solutions from the dye methylene blue (MB) are presented. The maximum activating effect was achieved as a result of acid treatment, which leads to a 38 % increase in the total acidity of the sorption material in comparison with the initial one. It is shown that the sorption isotherms of the dye on the initial and activated samples of TKSH500 have an S-shaped form. In the region of low dye concentrations, a monolayer is formed; with an increase in the dye content, sorption becomes polymolecular. Analysis of the IR spectra of sorption materials after adsorption of the MB dye showed a shift to the low-frequency region of the positions of the bands in the regions corresponding to the vibrations of the O–H and C = O bonds, which indicates the ionization of hydroxyl and carboxyl groups present in the sorption materials, and the formation of a bond between them and the MB molecule.
Petroleum products belong to the most common man-made pollutants of surface watercourses, and sometimes even underground drinking water sources. They get to the environment at the extraction and transportation of oil and oil products, as well as at industrial disasters. The oil-contaminated sewage waters produce the general-toxic, embryotoxic and carcinogenic effect, and weaken the immune system. To purify wastewaters from petroleum products the most efficient and environmentally friendly is the sorption method. This paper considers using a carbon-containing material, obtained by thermal modification at 450°C of waste kieselguhr sludge from vegetable oil extraction industry, as petroleum sorbent. The designed sorbent is characterized with mesoporous structure, high hydrophobic properties and the presence of oxygen-containing functional groups – carboxyl, hydroxyl and lactone – on the carbon layer surface. Research has been carried out in purification of test water media from emulsified petroleum products in dynamic conditions with the use of the designed sorbent. The number of passed sorption volumes to the «breakthrough» and the full saturation of the sorbent with oil products were determined. The calculated dynamic exchange capacity of the sorbent for petroleum products is 2.9 mg/g, the total exchange capacity – 8.4 mg/g. The limiting stage of petroleum products sorption process kinetics with the carbon-containing sorption material in the studied conditions is diffusion inside the sorbent grains.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.