Technologically the electrochemical deposition method through the influence of potential, temperature, pH and composition of reactants offers excellent control lover the properties of semiconductors Using a potentiostatic approach, the films of CdS were deposited on t i n oxide coated glass substrates at merent conditions. The films were found to be smooth, uniform and adherent 114th a small grain size. X-ray &tion analysis indicated a hexagonal phase rather than the cubic phase.Electrochemica1 deposition parameters were studied to
We investigated the effect of CdCl2 treatment of CdS films on the photovoltaic performance of polycrystalline CdTe/CdS solar cells. X-ray diffraction studies indicated that the diffusion of S into CdTe is qualitatively the same for CdTe/CdS films fabricated with both as-deposited and CdCl2-treated CdS. A major difference was observed in the extent of Te diffusion into CdS for the two types of CdS films. Full conversion of CdS into CdS1-yTey; was observed for films prepared with asdeposited CdS, while the formation of the ternary phase was below the detection limit for films prepared with CdCl2-treated CdS. Photoluminescence measurements confirmed this result. The difference in interdiffusion leads to differences in optical transmission of CdS films and spectral response of CdTe/CdS solar cells. An increase of 2.7 mA/cm2 in short-circuit current density was observed as a result of improved spectral response in the wavelength range of 500–600 nm for the CdCl2-treated CdS.
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