Die aus den Aminoguanidinen (I) und Aceton (II) in Gegenwart von Natriumhydrid dargestellten Verbindungen (III) liefern mit den Isothiocyanaten (IV) die Isopropylidenamino‐amidino‐thioharnstoffe (V ), die sich durch Erhitzen mit Natronlauge oder Essigsäure zu den 1,2,4‐Triazolen (VI) cyclisieren lassen.
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