It is well known that applying an electric field to a flame can affect its propagation speed, stability, and combustion chemistry. External electrodes, arc discharges, plasma jets, and corona discharges have been employed to allow combustible gas mixtures to operate outside their flammability limits or to increase combustion speed. Previously reported experiments have involved silent electrical discharges applied to propagating flames. These demonstrated that the flame propagation velocity can be increased when the discharge is applied to the unburned gas mixture upstream of a flame. In contrast, the work reported here used a coaxial-cylinder, nonthermal, silent discharge plasma reactor to activate a propane gas stream before it was mixed with air and ignited. With the plasma, the physical appearance of the flame changes (increased stability) and substantial changes in mass spectrometer peaks are observed, indicating that the combustion process is enhanced with the application of the plasma.
As adaptable as polymeric materials are in their many applications to our daily lives, the need exists to tailor the polymer surfaces to provide even more flexibility in regard to their uses. Plasma treatments offer an unprecedented spectrum of possible surface modifications to enhance polymers, ranging from simple topographical changes to creation of surface chemistries and coatings that are radically different from the bulk polymer. Furthermore plasma treatments are environmentally friendly and economical in regard to their use of materials.Plasma processing can be classified into at least four categories that often overlap. These are the following: (1) surface preparation by breakdown of surface oils and loose contaminates, (2) etching of new topographies, (3) surface activation by creation or grafting of new functional groups or chemically reactive, excited metastable species on the surface, and (4) deposition of monolithic, adherent surface coatings by polymerization of monomeric species on the surface. Key features of these processes will be briefly discussed, with a rudimentary introduction to the chemistries involved, as well as examples. Focus is placed on capacitively coupled radio-frequency (rf) plasmas (see Figure 1 in the article by Lieberman et al. in this issue of MRS Bulletin) since they are most commonly used in polymer treatment.
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